Effective Size and Zeta Potential of Nanorods by Ferguson Analysis
The effective hydrodynamic size and free mobility of particles of varying aspect ratio were evaluated by Ferguson analysis of gel electrophoresis. The ligand layer thickness was estimated from the difference between the effective size and the size of the metal core from TEM imaging. The zeta potenti...
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American Chemical Society
2011
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Online Access: | http://hdl.handle.net/1721.1/65164 https://orcid.org/0000-0003-0874-4584 |
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author | Park, Sunho Sinha, Niraj Hamad-Schifferli, Kimberly |
author2 | Massachusetts Institute of Technology. Department of Biological Engineering |
author_facet | Massachusetts Institute of Technology. Department of Biological Engineering Park, Sunho Sinha, Niraj Hamad-Schifferli, Kimberly |
author_sort | Park, Sunho |
collection | MIT |
description | The effective hydrodynamic size and free mobility of particles of varying aspect ratio were evaluated by Ferguson analysis of gel electrophoresis. The ligand layer thickness was estimated from the difference between the effective size and the size of the metal core from TEM imaging. The zeta potential of the particles was calculated from the Ferguson analysis result by applying conventional electrophoresis theories for spheres and cylinders. The results show that Henry’s solution for spherical particles can be used to obtain the zeta potential of cylindrical particles without requiring the use of TEM for size analysis. |
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format | Article |
id | mit-1721.1/65164 |
institution | Massachusetts Institute of Technology |
language | en_US |
last_indexed | 2024-09-23T09:56:43Z |
publishDate | 2011 |
publisher | American Chemical Society |
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spelling | mit-1721.1/651642022-09-30T17:52:36Z Effective Size and Zeta Potential of Nanorods by Ferguson Analysis Park, Sunho Sinha, Niraj Hamad-Schifferli, Kimberly Massachusetts Institute of Technology. Department of Biological Engineering Massachusetts Institute of Technology. Department of Mechanical Engineering Hamad-Schifferli, Kimberly Park, Sunho Sinha, Niraj Hamad-Schifferli, Kimberly The effective hydrodynamic size and free mobility of particles of varying aspect ratio were evaluated by Ferguson analysis of gel electrophoresis. The ligand layer thickness was estimated from the difference between the effective size and the size of the metal core from TEM imaging. The zeta potential of the particles was calculated from the Ferguson analysis result by applying conventional electrophoresis theories for spheres and cylinders. The results show that Henry’s solution for spherical particles can be used to obtain the zeta potential of cylindrical particles without requiring the use of TEM for size analysis. National Science Foundation (U.S.) (DMR 0906838) 2011-08-16T13:46:46Z 2011-08-16T13:46:46Z 2010-07 Article http://purl.org/eprint/type/JournalArticle 0743-7463 1520-5827 http://hdl.handle.net/1721.1/65164 Park, Sunho, Niraj Sinha, and Kimberly Hamad-Schifferli. “Effective Size and Zeta Potential of Nanorods by Ferguson Analysis.” Langmuir 26.16 (2010) : 13071-13075. https://orcid.org/0000-0003-0874-4584 en_US http://dx.doi.org/10.1021/la1024108 Langmuir Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society Prof. Hamad-Schifferli |
spellingShingle | Park, Sunho Sinha, Niraj Hamad-Schifferli, Kimberly Effective Size and Zeta Potential of Nanorods by Ferguson Analysis |
title | Effective Size and Zeta Potential of Nanorods by Ferguson Analysis |
title_full | Effective Size and Zeta Potential of Nanorods by Ferguson Analysis |
title_fullStr | Effective Size and Zeta Potential of Nanorods by Ferguson Analysis |
title_full_unstemmed | Effective Size and Zeta Potential of Nanorods by Ferguson Analysis |
title_short | Effective Size and Zeta Potential of Nanorods by Ferguson Analysis |
title_sort | effective size and zeta potential of nanorods by ferguson analysis |
url | http://hdl.handle.net/1721.1/65164 https://orcid.org/0000-0003-0874-4584 |
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