Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 2011.
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| Format: | Thesis |
| Language: | eng |
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Massachusetts Institute of Technology
2011
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| Online Access: | http://hdl.handle.net/1721.1/65167 |
| _version_ | 1811081686908141568 |
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| author | Yu, Tony S. (Tony Sheung) |
| author2 | Anette E. Hosoi. |
| author_facet | Anette E. Hosoi. Yu, Tony S. (Tony Sheung) |
| author_sort | Yu, Tony S. (Tony Sheung) |
| collection | MIT |
| description | Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 2011. |
| first_indexed | 2024-09-23T11:50:53Z |
| format | Thesis |
| id | mit-1721.1/65167 |
| institution | Massachusetts Institute of Technology |
| language | eng |
| last_indexed | 2024-09-23T11:50:53Z |
| publishDate | 2011 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/651672019-04-12T13:31:36Z Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing Growing Alq₃ needles via methanol-vapor annealing Yu, Tony S. (Tony Sheung) Anette E. Hosoi. Massachusetts Institute of Technology. Dept. of Mechanical Engineering. Massachusetts Institute of Technology. Dept. of Mechanical Engineering. Mechanical Engineering. Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 2011. This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. Cataloged from student submitted PDF version of thesis. Includes bibliographical references (p. 135-145). Organic electronics hold the promise of low-cost, flexible, large-area electronic and optoelectronic devices. In order to improve the performance of these devices, it is vital to control the morphology (e.g., the crystallinity) of these thin films. This thesis examines how solvent-vapor annealing of thin, amorphous films of Alq₃-i.e., tris-(8-hydroxyquinoline) aluminum-promotes the growth of single-crystal needles; we explore this system through experiments, modeling, and analytical scaling laws. The first part of this thesis describes the growth of single-crystal Alq₃ needles from amorphous, thin films of Alq₃ annealed in methanol vapor. Micrographs captured during annealing reveal needle lengths that grow like power laws, such that Lneedle ~ t[gamma]. We show that the growth exponent, [gamma], decreases when the thickness of the Alq₃ films is increased. In addition to needle growth, the fluid films exhibited dewetting and coarsening behavior: the initially-uniform films broke up into small drops that coalesced to form larger drops. In the second part of this thesis, we develop a mathematical model describing these morphological changes-both drop formation and needle growth-during solvent-vapor annealing. The evolution of the fluid films is modeled by a lubrication equation, and a convection-diffusion equation captures the transport of Alq3 and methanol within the films. We define a dimensionless transport coefficient, [alpha], which describes the relative effects of diffusion and coarsening-driven convection. Numerical simulations based on this 1D model reproduce the films evolution observed in experiments. The final part of this thesis describes scaling laws that govern needle growth. For large [alpha]-values, needle growth matched the theory of 1D, diffusion-driven solidification, such that [gamma]1/2. For low [alpha]-values, flow driven by drop collapses-i.e., coarsening-controls the growth of needles. Within this regime, we identify two cases: needles that were small compared to the typical drop size, and those that were large. For small needles, [gamma]-> 2/5, and for large needles, [gamma]-> 0:29. These scaling laws provide a simple physical picture of needle growth and match numerical simulations. by Tony S. Yu. Ph.D. 2011-08-16T15:24:12Z 2011-08-16T15:24:12Z 2011 2011 Thesis http://hdl.handle.net/1721.1/65167 744635987 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 145 p. application/pdf Massachusetts Institute of Technology |
| spellingShingle | Mechanical Engineering. Yu, Tony S. (Tony Sheung) Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing |
| title | Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing |
| title_full | Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing |
| title_fullStr | Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing |
| title_full_unstemmed | Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing |
| title_short | Solidification in a thin liquid film : growing Alq₃ needles via methanol-vapor annealing |
| title_sort | solidification in a thin liquid film growing alq₃ needles via methanol vapor annealing |
| topic | Mechanical Engineering. |
| url | http://hdl.handle.net/1721.1/65167 |
| work_keys_str_mv | AT yutonystonysheung solidificationinathinliquidfilmgrowingalq3needlesviamethanolvaporannealing AT yutonystonysheung growingalq3needlesviamethanolvaporannealing |