Nuclear magnetic resonance-based study of ordered layering on the surface of alumina nanoparticles in water

Layering of water molecules on the surface of alumina nanoparticles in an alumina/water nanofluid is studied using nuclear magnetic resonance (NMR). The data suggest that a thin ordered layer ( ∼ 1.4 nm) of water molecules surrounds each nanoparticle. This ordered layer increases the nanoparticle ef...

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Bibliographic Details
Main Authors: Gerardi, Craig, Cory, David G., Buongiorno, Jacopo, Hu, Lin-Wen, McKrell, Thomas J.
Other Authors: Massachusetts Institute of Technology. Department of Nuclear Science and Engineering
Format: Article
Language:en_US
Published: American Institute of Physics 2011
Online Access:http://hdl.handle.net/1721.1/66179
Description
Summary:Layering of water molecules on the surface of alumina nanoparticles in an alumina/water nanofluid is studied using nuclear magnetic resonance (NMR). The data suggest that a thin ordered layer ( ∼ 1.4 nm) of water molecules surrounds each nanoparticle. This ordered layer increases the nanoparticle effective volumetric fraction; however, the nanofluid thermal conductivity appears to be unaffected by this layer, and in good agreement with Maxwell’s effective medium theory. Furthermore, the NMR data suggest that the nanoparticles do not enhance, but rather stifle micromixing in the base fluid.