Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion
It's just a phase: A highly fluorinated compound with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of...
| Main Authors: | , |
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| Format: | Article |
| Language: | en_US |
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Wiley-VCH Verlag GmbH & Co. KGaA
2011
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| Online Access: | http://hdl.handle.net/1721.1/67823 |
| _version_ | 1811075568664313856 |
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| author | Lim, Jeewoo Swager, Timothy Manning |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Lim, Jeewoo Swager, Timothy Manning |
| author_sort | Lim, Jeewoo |
| collection | MIT |
| description | It's just a phase: A highly fluorinated compound with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of the polymer could be processed into aqueous emulsions that display high fluorescence quantum yields (see picture). |
| first_indexed | 2024-09-23T10:08:02Z |
| format | Article |
| id | mit-1721.1/67823 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T10:08:02Z |
| publishDate | 2011 |
| publisher | Wiley-VCH Verlag GmbH & Co. KGaA |
| record_format | dspace |
| spelling | mit-1721.1/678232022-09-30T19:06:26Z Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion Lim, Jeewoo Swager, Timothy Manning Massachusetts Institute of Technology. Department of Chemistry Swager, Timothy Manning Lim, Jeewoo Swager, Timothy Manning It's just a phase: A highly fluorinated compound with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of the polymer could be processed into aqueous emulsions that display high fluorescence quantum yields (see picture). United States. Army Research Office (Institute for Soldier Nanotechnologies) 2011-12-19T20:48:27Z 2011-12-19T20:48:27Z 2010-09 2010-07 Article http://purl.org/eprint/type/JournalArticle 1521-3773 http://hdl.handle.net/1721.1/67823 Lim, J. and Swager, T. M. (2010), Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion. Angewandte Chemie International Edition, 49: 7486–7488. doi: 10.1002/anie.201003111 en_US http://dx.doi.org/10.1002/anie.201003111 Angewandte Chemie International Edition Creative Commons Attribution-Noncommercial-Share Alike 3.0 http://creativecommons.org/licenses/by-nc-sa/3.0/ application/pdf Wiley-VCH Verlag GmbH & Co. KGaA Prof. Swager |
| spellingShingle | Lim, Jeewoo Swager, Timothy Manning Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion |
| title | Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion |
| title_full | Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion |
| title_fullStr | Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion |
| title_full_unstemmed | Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion |
| title_short | Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion |
| title_sort | fluorous biphase synthesis of a poly p phenyleneethynylene and its fluorescent aqueous fluorous phase emulsion |
| url | http://hdl.handle.net/1721.1/67823 |
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