Shape memory and superelasticity in polycrystalline Cu-Al-Ni microwires

We report a strategy to significantly improve the ductility and achieve large superelastic and shape memory strains in polycrystalline Cu–Al–Ni shape memory alloys that are normally brittle. We use a liquid-phase (Taylor) wire forming process to obtain microwires of 10–150 μm diameter with a bamboo...

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Bibliographic Details
Main Authors: Chen, Ying, Zhang, Xuexi, Dunand, David C., Schuh, Christopher A.
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering
Format: Article
Language:en_US
Published: American Institute of Physics 2012
Online Access:http://hdl.handle.net/1721.1/69218
https://orcid.org/0000-0001-9856-2682
Description
Summary:We report a strategy to significantly improve the ductility and achieve large superelastic and shape memory strains in polycrystalline Cu–Al–Ni shape memory alloys that are normally brittle. We use a liquid-phase (Taylor) wire forming process to obtain microwires of 10–150 μm diameter with a bamboo grain structure. The reduction of grain boundary area, removal of triple junctions, and introduction of a high specific surface area in the wire decrease constraints on the martensitic transformation, and permit both superelasticity and stress-assisted two-way shape memory with recoverable strains as high as 6.8%.