Synthesis of DiamidoPyrrolyl Molybdenum Complexes Relevant to Reduction of Dinitrogen to Ammonia
A potentially useful trianionic ligand for the reduction of dinitrogen catalytically by molybdenum complexes is one in which one of the arms in a [(RNCH2CH2)3N]3− ligand is replaced by a 2-mesitylpyrrolyl-α-methyl arm, that is, [(RNCH2CH2)2NCH2(2-MesitylPyrrolyl)]3− (R = C6F5, 3,5-Me2C6H3, or 3,5-t-...
Main Authors: | Chin, Jia Min, Schrock, Richard Royce, Muller, Peter |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society
2012
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Online Access: | http://hdl.handle.net/1721.1/69555 https://orcid.org/0000-0001-5827-3552 |
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