Synthesis of DiamidoPyrrolyl Molybdenum Complexes Relevant to Reduction of Dinitrogen to Ammonia

A potentially useful trianionic ligand for the reduction of dinitrogen catalytically by molybdenum complexes is one in which one of the arms in a [(RNCH2CH2)3N]3− ligand is replaced by a 2-mesitylpyrrolyl-α-methyl arm, that is, [(RNCH2CH2)2NCH2(2-MesitylPyrrolyl)]3− (R = C6F5, 3,5-Me2C6H3, or 3,5-t-...

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Bibliographic Details
Main Authors: Chin, Jia Min, Schrock, Richard Royce, Muller, Peter
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society 2012
Online Access:http://hdl.handle.net/1721.1/69555
https://orcid.org/0000-0001-5827-3552

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