Synthesis of Cis,Syndiotactic ROMP Polymers Containing Alternating Enantiomers

Ring-opening metathesis polymerization (ROMP) of rac-endo,exo-5,6-dicarbomethoxynorbornene (inter alia) yields a cis,syndio,alt-polymer, one in which the sequential units in the cis,syndiotactic polymer consist of alternating enantiomers. Cis selectivity arises through addition of the monomer to pro...

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Bibliographic Details
Main Authors: Flook, Margaret M., Ng, Victor Wee Lin, Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society 2012
Online Access:http://hdl.handle.net/1721.1/69594
https://orcid.org/0000-0001-5827-3552