Endo-Selective Enyne Ring- Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes
The utility of W-alkylidene complexes for enyne ring-closing metathesis is demonstrated in a direct comparison with Mo-based analogs. Tungsten complexes lead to less alkyne oligomerization and higher levels of endo-selectivity and enantioselectivity.
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society
2012
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| Online Access: | http://hdl.handle.net/1721.1/69936 https://orcid.org/0000-0001-5827-3552 |