Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, 2012.
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | Thesis |
| Language: | eng |
| Published: |
Massachusetts Institute of Technology
2012
|
| Subjects: | |
| Online Access: | http://hdl.handle.net/1721.1/70774 |
| _version_ | 1811090934013624320 |
|---|---|
| author | McLean, Noah Morgan |
| author2 | Samuel A. Bowring. |
| author_facet | Samuel A. Bowring. McLean, Noah Morgan |
| author_sort | McLean, Noah Morgan |
| collection | MIT |
| description | Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, 2012. |
| first_indexed | 2024-09-23T14:54:14Z |
| format | Thesis |
| id | mit-1721.1/70774 |
| institution | Massachusetts Institute of Technology |
| language | eng |
| last_indexed | 2024-09-23T14:54:14Z |
| publishDate | 2012 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/707742019-04-11T08:29:27Z Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington McLean, Noah Morgan Samuel A. Bowring. Massachusetts Institute of Technology. Dept. of Earth, Atmospheric, and Planetary Sciences. Massachusetts Institute of Technology. Dept. of Earth, Atmospheric, and Planetary Sciences. Earth, Atmospheric, and Planetary Sciences. Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, 2012. Cataloged from PDF version of thesis. Includes bibliographical references (p. 173-186). The range of geologic problems that may be addressed by U-Pb geochronology is governed by the precision to which U-Pb dates can be measured, expressed as their estimated uncertainties. Accurate and precise knowledge of both the value and uncertainty of an isotopic date are imperative to its correct interpretation. This thesis focuses on quantitatively addressing the large volume of information that contributes to the calculation of published high-precision U-Pb dates. A new algorithm (Chapter 2) outlines the equations that transform measured isotope ratios, along with a host of laboratory and instrumental parameters, into a U-Pb date. The algorithm propagates all known random and systematic uncertainties, resulting in an adaptable framework will remain usable as analytical and computational advances change the main uncertainty contributions. The data reduction and uncertainty propagation algorithm, as well as a new method for calculating weighted means that correctly treats systematic uncertainties, have been incorporated into the open-source software program U-PbRedux. Chapter 3 explores the mechanisms of isotopic fractionation, the largest instrumental correction to measured U-Pb data, using a new linear regression algorithm. The algorithm rapidly regresses a straight line through large datasets in multiple dimensions using a novel simplification to the maximum likelihood objective equation, and is used to demonstrate that Pb undergoes mass-independent fractionation in the source of a thermal ionization mass spectrometer. Chapter 4 addresses the largest source of systematic uncertainty considered when confederating datasets from different labs, the calibration of the tracer used for isotope dilution. The calibration assumes only first-principles mass and purity measurements traceable to SI units, then defines a measurement model that utilizes >105 measurements in a series of overdetermined inverse problems to estimate the tracer isotopic composition. The result is a reduction by a factor of almost four in the tracer uncertainty contribution to a U-Pb date. In Chapter 5, I use the new algorithms to explore regional geology. High-precision U-Pb dates from the metamorphic core of the North Cascades and from ash beds in three fluvial basins that flank it show that Eocene magmatism, solid-state deformation, and exhumation of the metamorphic core are coincident with rapid basin subsidence. by Noah Morgan McLean. Ph.D. 2012-05-15T21:11:21Z 2012-05-15T21:11:21Z 2012 2012 Thesis http://hdl.handle.net/1721.1/70774 790610132 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 186 p. application/pdf n-us-wa Massachusetts Institute of Technology |
| spellingShingle | Earth, Atmospheric, and Planetary Sciences. McLean, Noah Morgan Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington |
| title | Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington |
| title_full | Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington |
| title_fullStr | Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington |
| title_full_unstemmed | Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington |
| title_short | Statistical considerations in high precision U-Pb geochronology, with an application to the tectonic evolution of the North Cascades, Washington |
| title_sort | statistical considerations in high precision u pb geochronology with an application to the tectonic evolution of the north cascades washington |
| topic | Earth, Atmospheric, and Planetary Sciences. |
| url | http://hdl.handle.net/1721.1/70774 |
| work_keys_str_mv | AT mcleannoahmorgan statisticalconsiderationsinhighprecisionupbgeochronologywithanapplicationtothetectonicevolutionofthenorthcascadeswashington |