Phase transition in the Jarzynski estimator of free energy differences
The transition between a regime in which thermodynamic relations apply only to ensembles of small systems coupled to a large environment and a regime in which they can be used to characterize individual macroscopic systems is analyzed in terms of the change in behavior of the Jarzynski estimator of...
Main Authors: | Suarez Gonzalez, Alberto, Silbey, Robert J., Oppenheim, Irwin |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Physical Society
2012
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Online Access: | http://hdl.handle.net/1721.1/71629 |
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