High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions
We report the dynamic nuclear polarization of 1H spins in magic-angle-spinning spectra recorded at 5 T and 84 K via the solid effect using Mn2+ and Gd[superscript 3+] complexes as polarizing agents. We show that the magnitude of the enhancements can be directly related to the effective line width of...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2012
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| Online Access: | http://hdl.handle.net/1721.1/72026 https://orcid.org/0000-0003-1589-832X |