High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions

High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions

We report the dynamic nuclear polarization of 1H spins in magic-angle-spinning spectra recorded at 5 T and 84 K via the solid effect using Mn2+ and Gd[superscript 3+] complexes as polarizing agents. We show that the magnitude of the enhancements can be directly related to the effective line width of...

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Bibliographic Details
Main Authors:	Barnes, Alexander, Corzilius, Bjorn, Griffin, Robert Guy, Bertini, Ivano, Luchinat, Claudio, Smith, Albert A.
Other Authors:	Massachusetts Institute of Technology. Department of Chemistry
Format:	Article
Language:	en_US
Published:	American Chemical Society (ACS) 2012
Online Access:	http://hdl.handle.net/1721.1/72026 https://orcid.org/0000-0003-1589-832X

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