Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts
3,5-Dimethylphenylimido complexes of tungsten can be prepared using procedures analogous to those employed for other tungsten catalysts, as can bispyrrolide species and MonoAryloxide-Pyrrolide (MAP) species. Homocouplings of 1-hexene, 1-octene, and methyl 10-undecenoate are achieved in 45−89% yield...
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| Format: | Article |
| Language: | en_US |
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American Chemical Society (ACS)
2012
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| Online Access: | http://hdl.handle.net/1721.1/72371 https://orcid.org/0000-0001-5827-3552 |
| _version_ | 1826191454455726080 |
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| author | Marinescu, Smaranda C. Schrock, Richard Royce Muller, Peter Takase, Michael K. Hoveyda, Amir H. |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Marinescu, Smaranda C. Schrock, Richard Royce Muller, Peter Takase, Michael K. Hoveyda, Amir H. |
| author_sort | Marinescu, Smaranda C. |
| collection | MIT |
| description | 3,5-Dimethylphenylimido complexes of tungsten can be prepared using procedures analogous to those employed for other tungsten catalysts, as can bispyrrolide species and MonoAryloxide-Pyrrolide (MAP) species. Homocouplings of 1-hexene, 1-octene, and methyl 10-undecenoate are achieved in 45−89% yield and a Z selectivity of >99% with W(NAr′′)(C[subscript 3]H[subscript 6])(pyr)(OHIPT) as a catalyst. Homocoupling of terminal olefins in the presence of (E)-olefins elsewhere in the molecule also was achieved with excellent selectivity. |
| first_indexed | 2024-09-23T08:56:07Z |
| format | Article |
| id | mit-1721.1/72371 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T08:56:07Z |
| publishDate | 2012 |
| publisher | American Chemical Society (ACS) |
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| spelling | mit-1721.1/723712022-09-30T12:15:58Z Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts Marinescu, Smaranda C. Schrock, Richard Royce Muller, Peter Takase, Michael K. Hoveyda, Amir H. Massachusetts Institute of Technology. Department of Chemistry Schrock, Richard Royce Marinescu, Smaranda C. Schrock, Richard Royce Muller, Peter Takase, Michael K. 3,5-Dimethylphenylimido complexes of tungsten can be prepared using procedures analogous to those employed for other tungsten catalysts, as can bispyrrolide species and MonoAryloxide-Pyrrolide (MAP) species. Homocouplings of 1-hexene, 1-octene, and methyl 10-undecenoate are achieved in 45−89% yield and a Z selectivity of >99% with W(NAr′′)(C[subscript 3]H[subscript 6])(pyr)(OHIPT) as a catalyst. Homocoupling of terminal olefins in the presence of (E)-olefins elsewhere in the molecule also was achieved with excellent selectivity. National Science Foundation (U.S.). (Grant number CHE-0841187) National Institutes of Health (U.S.) (Grant number GM-59426) 2012-08-28T16:05:08Z 2012-08-28T16:05:08Z 2011-03 2011-02 Article http://purl.org/eprint/type/JournalArticle 0276-7333 1520-6041 http://hdl.handle.net/1721.1/72371 Marinescu, Smaranda C. et al. “Room-Temperature Z-Selective Homocoupling of α-Olefins by Tungsten Catalysts.” Organometallics 30.7 (2011): 1780–1782. https://orcid.org/0000-0001-5827-3552 en_US http://dx.doi.org/10.1021/om200150c Organometallics Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) PMC |
| spellingShingle | Marinescu, Smaranda C. Schrock, Richard Royce Muller, Peter Takase, Michael K. Hoveyda, Amir H. Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts |
| title | Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts |
| title_full | Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts |
| title_fullStr | Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts |
| title_full_unstemmed | Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts |
| title_short | Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts |
| title_sort | room temperature z selective homocoupling of alpha olefins by tungsten catalysts |
| url | http://hdl.handle.net/1721.1/72371 https://orcid.org/0000-0001-5827-3552 |
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