Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts
3,5-Dimethylphenylimido complexes of tungsten can be prepared using procedures analogous to those employed for other tungsten catalysts, as can bispyrrolide species and MonoAryloxide-Pyrrolide (MAP) species. Homocouplings of 1-hexene, 1-octene, and methyl 10-undecenoate are achieved in 45−89% yield...
Main Authors: | Marinescu, Smaranda C., Schrock, Richard Royce, Muller, Peter, Takase, Michael K., Hoveyda, Amir H. |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2012
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Online Access: | http://hdl.handle.net/1721.1/72371 https://orcid.org/0000-0001-5827-3552 |
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