Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes

Carbon nanotubes (CNTs) are a potential new component to be incorporated into existing aerospace structural composites for multifunctional (mechanical, electrical, thermal, etc.) property enhancement. Although CNT properties are extraordinary when measured individually, they tend to degrade by a...

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Main Authors: Yamamoto, Namiko, Guzman de Villoria, Roberto, Cebeci, Hulya Geyik, Wardle, Brian L.
Other Authors: Massachusetts Institute of Technology. Department of Aeronautics and Astronautics
Format: Article
Language:en_US
Published: American Institute of Aeronautics and Astronautics 2012
Online Access:http://hdl.handle.net/1721.1/72572
https://orcid.org/0000-0003-3530-5819
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author Yamamoto, Namiko
Guzman de Villoria, Roberto
Cebeci, Hulya Geyik
Wardle, Brian L.
author2 Massachusetts Institute of Technology. Department of Aeronautics and Astronautics
author_facet Massachusetts Institute of Technology. Department of Aeronautics and Astronautics
Yamamoto, Namiko
Guzman de Villoria, Roberto
Cebeci, Hulya Geyik
Wardle, Brian L.
author_sort Yamamoto, Namiko
collection MIT
description Carbon nanotubes (CNTs) are a potential new component to be incorporated into existing aerospace structural composites for multifunctional (mechanical, electrical, thermal, etc.) property enhancement. Although CNT properties are extraordinary when measured individually, they tend to degrade by a large factor when integrated in system (often in polymer matrices). Mechanisms and effectiveness of nano-scale CNT implementation into macro-scale structural composites are not well understood. Non-mechanical aspects of these composites are the focus of this work. As a CNT hybridized fiber polymer composite, fuzzy fiber reinforced plastic (FFRP) is developed using a scalable fabrication method that achieves uniform CNT distributions for thermal and electrical conductive networks without requiring intensive mixing which can damage CNTs. At small CNT volume fractions (~0.5- 8% Vf), characterization shows significant enhancement in electrical conduction (x106-108) but limited enhancement in thermal conduction (x1.9). In addition, aligned-CNT polymer nanocomposites (A-CNT-PNCs) are being characterized as a representative volume element (RVE) of the FFRP. Experimentally obtained data on consistent A-CNT-PNC samples sets provide engineering knowledge and to achieve effective utilization of CNTs' multifunctional properties. Theoretical studies, both analytical and numerical, have been recently developed, suggesting interface effects may be a key to explaining the above limitations, including electron tunneling/hopping or phonon scattering at CNT-CNT and CNT-polymer interfaces. Multiple test techniques and property extraction methods for A-CNT-PNCs are developed and/or employed for cross-comparison. Applications of nano-engineered composites enhanced with CNTs can include lightning protection layers, electromagnetic interference shields, thermal management layers, and thermoelectrical sensor layers for airplane structures.
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spelling mit-1721.1/725722022-10-01T01:45:31Z Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes Yamamoto, Namiko Guzman de Villoria, Roberto Cebeci, Hulya Geyik Wardle, Brian L. Massachusetts Institute of Technology. Department of Aeronautics and Astronautics Massachusetts Institute of Technology. Department of Materials Science and Engineering Wardle, Brian L. Yamamoto, Namiko Guzman de Villoria, Roberto Cebeci, Hulya Geyik Wardle, Brian L. Carbon nanotubes (CNTs) are a potential new component to be incorporated into existing aerospace structural composites for multifunctional (mechanical, electrical, thermal, etc.) property enhancement. Although CNT properties are extraordinary when measured individually, they tend to degrade by a large factor when integrated in system (often in polymer matrices). Mechanisms and effectiveness of nano-scale CNT implementation into macro-scale structural composites are not well understood. Non-mechanical aspects of these composites are the focus of this work. As a CNT hybridized fiber polymer composite, fuzzy fiber reinforced plastic (FFRP) is developed using a scalable fabrication method that achieves uniform CNT distributions for thermal and electrical conductive networks without requiring intensive mixing which can damage CNTs. At small CNT volume fractions (~0.5- 8% Vf), characterization shows significant enhancement in electrical conduction (x106-108) but limited enhancement in thermal conduction (x1.9). In addition, aligned-CNT polymer nanocomposites (A-CNT-PNCs) are being characterized as a representative volume element (RVE) of the FFRP. Experimentally obtained data on consistent A-CNT-PNC samples sets provide engineering knowledge and to achieve effective utilization of CNTs' multifunctional properties. Theoretical studies, both analytical and numerical, have been recently developed, suggesting interface effects may be a key to explaining the above limitations, including electron tunneling/hopping or phonon scattering at CNT-CNT and CNT-polymer interfaces. Multiple test techniques and property extraction methods for A-CNT-PNCs are developed and/or employed for cross-comparison. Applications of nano-engineered composites enhanced with CNTs can include lightning protection layers, electromagnetic interference shields, thermal management layers, and thermoelectrical sensor layers for airplane structures. Airbus Industrie Massachusetts Institute of Technology (Richard and Linda Hardy Graduate Fellowship) Boeing Company Empresa Brasileira de Aeronáutica Lockheed Martin Spirit AeroSystems (Firm) Textron, inc. Composite Systems Technology (Firm) Toho Tenax Co., Ltd. Massachusetts Institute of Technology (Nano-Engineered Composite aerospace STructures (NECST) Consortium) 2012-09-07T18:00:29Z 2012-09-07T18:00:29Z 2010-04 Article http://purl.org/eprint/type/ConferencePaper 9781617386138 1617386138 http://hdl.handle.net/1721.1/72572 Yamamoto, Namikonet al. "Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes." in Proceedings of the 51st AIAA/ASME/ASCE/AHS/ASC Structures, Structural Dynamics and Materials Conference, 2010, 12-15 April 2010, Orlando, Florida, USA, American Institute for Aeronautics and Astronautics (AIAA. https://orcid.org/0000-0003-3530-5819 en_US Proceedings of the 51st AIAA/ASME/ASCE/AHS/ASC Structures, Structural Dynamics and Materials Conference, 2010. Creative Commons Attribution-Noncommercial-Share Alike 3.0 http://creativecommons.org/licenses/by-nc-sa/3.0/ application/pdf American Institute of Aeronautics and Astronautics Wardle (via assistant)
spellingShingle Yamamoto, Namiko
Guzman de Villoria, Roberto
Cebeci, Hulya Geyik
Wardle, Brian L.
Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes
title Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes
title_full Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes
title_fullStr Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes
title_full_unstemmed Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes
title_short Thermal and Electrical Transport in Hybrid Woven Composites Reinforced with Aligned Carbon Nanotubes
title_sort thermal and electrical transport in hybrid woven composites reinforced with aligned carbon nanotubes
url http://hdl.handle.net/1721.1/72572
https://orcid.org/0000-0003-3530-5819
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AT cebecihulyageyik thermalandelectricaltransportinhybridwovencompositesreinforcedwithalignedcarbonnanotubes
AT wardlebrianl thermalandelectricaltransportinhybridwovencompositesreinforcedwithalignedcarbonnanotubes