Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer

The authors investigated a contrast enhancement behavior of hydrogen silsesquioxane (HSQ) in a salty development system (NaOH/NaCl). Time-resolved analysis of contrast curves and line-grating patterns were carried out to investigate the unique properties of a salty development process. In NaOH devel...

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Main Authors: Nam, Sung-Wook, Rooks, Michael J., Yang, Joel K. W., Berggren, Karl K., Kim, Hyun-Mi, Lee, Min-Hyun, Kim, Ki-Bum, Sim, Jae Hwan, Yoon, Do Yeung
Other Authors: Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Format: Article
Language:en_US
Published: American Vacuum Society (AVS) 2012
Online Access:http://hdl.handle.net/1721.1/74146
https://orcid.org/0000-0001-7453-9031
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author Nam, Sung-Wook
Rooks, Michael J.
Yang, Joel K. W.
Berggren, Karl K.
Kim, Hyun-Mi
Lee, Min-Hyun
Kim, Ki-Bum
Sim, Jae Hwan
Yoon, Do Yeung
author2 Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
author_facet Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Nam, Sung-Wook
Rooks, Michael J.
Yang, Joel K. W.
Berggren, Karl K.
Kim, Hyun-Mi
Lee, Min-Hyun
Kim, Ki-Bum
Sim, Jae Hwan
Yoon, Do Yeung
author_sort Nam, Sung-Wook
collection MIT
description The authors investigated a contrast enhancement behavior of hydrogen silsesquioxane (HSQ) in a salty development system (NaOH/NaCl). Time-resolved analysis of contrast curves and line-grating patterns were carried out to investigate the unique properties of a salty development process. In NaOH developer without salt, the development process was saturated beyond a certain development time. On the other hand, the addition of salt enabled a continuous development, which was not observed in the pure NaOH development. The continuous thinning process enhances the contrast of HSQ in the salty developer, which allows a fast collapsing behavior in HSQ line-grating patterns. During development process, salt seems to have the role of modifying HSQ by breaking network bonds preferentially, leading to a continuous development rate.
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spelling mit-1721.1/741462022-09-28T17:02:56Z Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer Nam, Sung-Wook Rooks, Michael J. Yang, Joel K. W. Berggren, Karl K. Kim, Hyun-Mi Lee, Min-Hyun Kim, Ki-Bum Sim, Jae Hwan Yoon, Do Yeung Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science Yang, Joel K. W. Berggren, Karl K. The authors investigated a contrast enhancement behavior of hydrogen silsesquioxane (HSQ) in a salty development system (NaOH/NaCl). Time-resolved analysis of contrast curves and line-grating patterns were carried out to investigate the unique properties of a salty development process. In NaOH developer without salt, the development process was saturated beyond a certain development time. On the other hand, the addition of salt enabled a continuous development, which was not observed in the pure NaOH development. The continuous thinning process enhances the contrast of HSQ in the salty developer, which allows a fast collapsing behavior in HSQ line-grating patterns. During development process, salt seems to have the role of modifying HSQ by breaking network bonds preferentially, leading to a continuous development rate. 2012-10-19T14:13:58Z 2012-10-19T14:13:58Z 2009-12 Article http://purl.org/eprint/type/JournalArticle 1071-1023 1520-8567 http://hdl.handle.net/1721.1/74146 Nam, Sung-Wook et al. “Contrast Enhancement Behavior of Hydrogen Silsesquioxane in a Salty Developer.” Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures 27.6 (2009): 2635. © 2009 American Vacuum Society https://orcid.org/0000-0001-7453-9031 en_US http://dx.doi.org/10.1116/1.3245991 Journal of Vacuum Science and Technology B Microelectronics and Nanometer Structures Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Vacuum Society (AVS) MIT web domain
spellingShingle Nam, Sung-Wook
Rooks, Michael J.
Yang, Joel K. W.
Berggren, Karl K.
Kim, Hyun-Mi
Lee, Min-Hyun
Kim, Ki-Bum
Sim, Jae Hwan
Yoon, Do Yeung
Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer
title Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer
title_full Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer
title_fullStr Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer
title_full_unstemmed Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer
title_short Contrast enhancement behavior of hydrogen silsesquioxane in a salty developer
title_sort contrast enhancement behavior of hydrogen silsesquioxane in a salty developer
url http://hdl.handle.net/1721.1/74146
https://orcid.org/0000-0001-7453-9031
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