Spin properties of very shallow nitrogen vacancy defects in diamond

We investigate spin and optical properties of individual nitrogen vacancy centers located within 1–10 nm from the diamond surface. We observe stable defects with a characteristic optically detected magnetic-resonance spectrum down to the lowest depth. We also find a small but systematic spectral bro...

Full description

Bibliographic Details
Main Authors: Ofori-Okai, Benjamin Kwasi, Tao, Ye, Ph. D. Massachusetts Institute of Technology, Pezzagna, S., Chang, K., Loretz, M., Schirhagl, R., Moores, B. A., Groot-Berning, K., Meijer, J., Degen, Christian
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Physical Society 2012
Online Access:http://hdl.handle.net/1721.1/74508
https://orcid.org/0000-0002-0737-6786
https://orcid.org/0000-0003-0018-7584
Description
Summary:We investigate spin and optical properties of individual nitrogen vacancy centers located within 1–10 nm from the diamond surface. We observe stable defects with a characteristic optically detected magnetic-resonance spectrum down to the lowest depth. We also find a small but systematic spectral broadening for defects shallower than about 2 nm. This broadening is consistent with the presence of a surface paramagnetic impurity layer [ Tisler et al. ACS Nano 3 1959 (2009)] largely decoupled by motional averaging. The observation of stable and well-behaved defects very close to the surface is critical for single-spin sensors and devices requiring nanometer proximity to the target.