Graphene Oxide as an Electrophile for Carbon Nucleophiles

The covalent, surface functionalization of graphene oxide with the malononitrile anion has been demonstrated. Once installed, these surface-bound “molecular lynchpins” can be chemically modified to increase the solubility of the graphene derivative in either organic or aqueous environments.

Bibliographic Details
Main Authors: Swager, Timothy Manning, Schmois, Ezequiel, Collins, William R.
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:en_US
Published: Royal Society of Chemistry 2012
Online Access:http://hdl.handle.net/1721.1/74528
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author Swager, Timothy Manning
Schmois, Ezequiel
Collins, William R.
author2 Massachusetts Institute of Technology. Department of Chemical Engineering
author_facet Massachusetts Institute of Technology. Department of Chemical Engineering
Swager, Timothy Manning
Schmois, Ezequiel
Collins, William R.
author_sort Swager, Timothy Manning
collection MIT
description The covalent, surface functionalization of graphene oxide with the malononitrile anion has been demonstrated. Once installed, these surface-bound “molecular lynchpins” can be chemically modified to increase the solubility of the graphene derivative in either organic or aqueous environments.
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spelling mit-1721.1/745282022-09-26T16:26:19Z Graphene Oxide as an Electrophile for Carbon Nucleophiles Swager, Timothy Manning Schmois, Ezequiel Collins, William R. Massachusetts Institute of Technology. Department of Chemical Engineering Massachusetts Institute of Technology. Department of Chemistry Swager, Timothy M. Swager, Timothy Manning Schmois, Ezequiel Collins, William R. The covalent, surface functionalization of graphene oxide with the malononitrile anion has been demonstrated. Once installed, these surface-bound “molecular lynchpins” can be chemically modified to increase the solubility of the graphene derivative in either organic or aqueous environments. United States. Intelligence Community (IC) Postdoctoral Research Fellowship Program Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies (Contract W911NF-07-D-004) 2012-10-31T17:19:30Z 2012-10-31T17:19:30Z 2011-07 2011-05 Article http://purl.org/eprint/type/JournalArticle 1359-7345 1364-548X http://hdl.handle.net/1721.1/74528 Collins, William R., Ezequiel Schmois, and Timothy M. Swager. “Graphene Oxide as an Electrophile for Carbon Nucleophiles.” Chemical Communications 47.31 (2011): 8790. en_US http://dx.doi.org/10.1039/c1cc12829a Chemical Communications Creative Commons Attribution-Noncommercial-Share Alike 3.0 http://creativecommons.org/licenses/by-nc-sa/3.0/ application/pdf Royal Society of Chemistry Prof. Swager via Erja Kajosalo
spellingShingle Swager, Timothy Manning
Schmois, Ezequiel
Collins, William R.
Graphene Oxide as an Electrophile for Carbon Nucleophiles
title Graphene Oxide as an Electrophile for Carbon Nucleophiles
title_full Graphene Oxide as an Electrophile for Carbon Nucleophiles
title_fullStr Graphene Oxide as an Electrophile for Carbon Nucleophiles
title_full_unstemmed Graphene Oxide as an Electrophile for Carbon Nucleophiles
title_short Graphene Oxide as an Electrophile for Carbon Nucleophiles
title_sort graphene oxide as an electrophile for carbon nucleophiles
url http://hdl.handle.net/1721.1/74528
work_keys_str_mv AT swagertimothymanning grapheneoxideasanelectrophileforcarbonnucleophiles
AT schmoisezequiel grapheneoxideasanelectrophileforcarbonnucleophiles
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