Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits
Polycyclic aromatic monomers based on substituted dibenz[a,h]anthracene frameworks have been prepared in high yields. From these, several fluorescent stair-stepped conjugated polymers containing fused aromatic subunits have been synthesized via Sonogashira polycondensations and Glaser-type oxidative...
| Main Authors: | , , |
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| Format: | Article |
| Language: | en_US |
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American Chemical Society (ACS)
2012
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| Online Access: | http://hdl.handle.net/1721.1/74530 |
| _version_ | 1826208730147979264 |
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| author | Chan, Julian M. W. Swager, Timothy M Kooi, Steven E |
| author2 | Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies |
| author_facet | Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies Chan, Julian M. W. Swager, Timothy M Kooi, Steven E |
| author_sort | Chan, Julian M. W. |
| collection | MIT |
| description | Polycyclic aromatic monomers based on substituted dibenz[a,h]anthracene frameworks have been prepared in high yields. From these, several fluorescent stair-stepped conjugated polymers containing fused aromatic subunits have been synthesized via Sonogashira polycondensations and Glaser-type oxidative couplings. The new polymers were characterized by NMR spectroscopy, gel-permeation chromatography (GPC), UV−vis, and fluorescence spectroscopy. |
| first_indexed | 2024-09-23T14:11:03Z |
| format | Article |
| id | mit-1721.1/74530 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T14:11:03Z |
| publishDate | 2012 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/745302022-10-01T19:38:32Z Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits Chan, Julian M. W. Swager, Timothy M Kooi, Steven E Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies Massachusetts Institute of Technology. Department of Chemistry Swager, Timothy M. Swager, Timothy Manning Chan, Julian M. W. Kooi, Steven Earl Polycyclic aromatic monomers based on substituted dibenz[a,h]anthracene frameworks have been prepared in high yields. From these, several fluorescent stair-stepped conjugated polymers containing fused aromatic subunits have been synthesized via Sonogashira polycondensations and Glaser-type oxidative couplings. The new polymers were characterized by NMR spectroscopy, gel-permeation chromatography (GPC), UV−vis, and fluorescence spectroscopy. National Science Foundation (U.S.). Division of Materials Research 2012-10-31T17:38:09Z 2012-10-31T17:38:09Z 2010-02 2010-02 Article http://purl.org/eprint/type/JournalArticle 0024-9297 1520-5835 http://hdl.handle.net/1721.1/74530 Chan, Julian M. W., Steven E. Kooi, and Timothy M. Swager. “Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits.” Macromolecules 43.6 (2010): 2789–2793. en_US http://dx.doi.org/ 10.1021/ma902486y Macromolecules Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) Prof. Swager via Erja Kajosalo |
| spellingShingle | Chan, Julian M. W. Swager, Timothy M Kooi, Steven E Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits |
| title | Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits |
| title_full | Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits |
| title_fullStr | Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits |
| title_full_unstemmed | Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits |
| title_short | Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits |
| title_sort | synthesis of stair stepped polymers containing dibenz a h anthracene subunits |
| url | http://hdl.handle.net/1721.1/74530 |
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