Nonequilibrium Thermodynamics of Porous Electrodes
We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic fluxes, and faradaic charge-transfer kinetics to the variational electrochemical p...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
The Electrochemical Society
2013
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| Online Access: | http://hdl.handle.net/1721.1/77923 |