First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material

The continued drive for high performance lithium batteries has imposed stricter requirements on the electrolyte materials. Solid electrolytes comprising lithium super ionic conductor materials exhibit good safety and stability and are promising to replace current organic liquid electrolytes. One maj...

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Main Authors: Mo, Yifei, Ong, Shyue Ping, Ceder, Gerbrand
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2013
Online Access:http://hdl.handle.net/1721.1/80290
https://orcid.org/0000-0002-8162-4629
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author Mo, Yifei
Ong, Shyue Ping
Ceder, Gerbrand
author2 Massachusetts Institute of Technology. Department of Materials Science and Engineering
author_facet Massachusetts Institute of Technology. Department of Materials Science and Engineering
Mo, Yifei
Ong, Shyue Ping
Ceder, Gerbrand
author_sort Mo, Yifei
collection MIT
description The continued drive for high performance lithium batteries has imposed stricter requirements on the electrolyte materials. Solid electrolytes comprising lithium super ionic conductor materials exhibit good safety and stability and are promising to replace current organic liquid electrolytes. One major limitation in the application of Li-ion conductors is that their typical conductivity is less than 10[superscript −4] S/cm at room temperature. Recently, Kamaya et al. reported a new Li super ionic conductor Li[subscript 10]GeP[subscript 2]S[subscript 12] (LGPS), which has the highest conductivity ever achieved among solid lithium electrolytes of 12 mS/cm at room temperature (comparable conductivity with liquid electrolytes) and outstanding electrochemical performance in Li batteries.
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spelling mit-1721.1/802902022-09-30T19:33:51Z First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material Mo, Yifei Ong, Shyue Ping Ceder, Gerbrand Massachusetts Institute of Technology. Department of Materials Science and Engineering Ceder, Gerbrand Mo, Yifei Ong, Shyue Ping Ceder, Gerbrand The continued drive for high performance lithium batteries has imposed stricter requirements on the electrolyte materials. Solid electrolytes comprising lithium super ionic conductor materials exhibit good safety and stability and are promising to replace current organic liquid electrolytes. One major limitation in the application of Li-ion conductors is that their typical conductivity is less than 10[superscript −4] S/cm at room temperature. Recently, Kamaya et al. reported a new Li super ionic conductor Li[subscript 10]GeP[subscript 2]S[subscript 12] (LGPS), which has the highest conductivity ever achieved among solid lithium electrolytes of 12 mS/cm at room temperature (comparable conductivity with liquid electrolytes) and outstanding electrochemical performance in Li batteries. Samsung Advanced Institute of Technology 2013-08-26T21:09:47Z 2013-08-26T21:09:47Z 2011-12 2011-12 Article http://purl.org/eprint/type/JournalArticle 0897-4756 1520-5002 http://hdl.handle.net/1721.1/80290 Mo, Yifei, Shyue Ping Ong, and Gerbrand Ceder. “First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material.” Chemistry of Materials 24, no. 1 (January 10, 2012): 15-17. https://orcid.org/0000-0002-8162-4629 en_US http://dx.doi.org/10.1021/cm203303y Chemistry of Materials Creative Commons Attribution-Noncommercial-Share Alike 3.0 http://creativecommons.org/licenses/by-nc-sa/3.0/ application/pdf American Chemical Society (ACS) Prof. Ceder via Angie Locknar
spellingShingle Mo, Yifei
Ong, Shyue Ping
Ceder, Gerbrand
First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
title First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
title_full First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
title_fullStr First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
title_full_unstemmed First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
title_short First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
title_sort first principles study of the li subscript 10 gep subscript 2 s subscript 12 lithium super ionic conductor material
url http://hdl.handle.net/1721.1/80290
https://orcid.org/0000-0002-8162-4629
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AT ongshyueping firstprinciplesstudyofthelisubscript10gepsubscript2ssubscript12lithiumsuperionicconductormaterial
AT cedergerbrand firstprinciplesstudyofthelisubscript10gepsubscript2ssubscript12lithiumsuperionicconductormaterial