First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
The continued drive for high performance lithium batteries has imposed stricter requirements on the electrolyte materials. Solid electrolytes comprising lithium super ionic conductor materials exhibit good safety and stability and are promising to replace current organic liquid electrolytes. One maj...
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American Chemical Society (ACS)
2013
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Online Access: | http://hdl.handle.net/1721.1/80290 https://orcid.org/0000-0002-8162-4629 |
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author | Mo, Yifei Ong, Shyue Ping Ceder, Gerbrand |
author2 | Massachusetts Institute of Technology. Department of Materials Science and Engineering |
author_facet | Massachusetts Institute of Technology. Department of Materials Science and Engineering Mo, Yifei Ong, Shyue Ping Ceder, Gerbrand |
author_sort | Mo, Yifei |
collection | MIT |
description | The continued drive for high performance lithium batteries has imposed stricter requirements on the electrolyte materials. Solid electrolytes comprising lithium super ionic conductor materials exhibit good safety and stability and are promising to replace current organic liquid electrolytes. One major limitation in the application of Li-ion conductors is that their typical conductivity is less than 10[superscript −4] S/cm at room temperature. Recently, Kamaya et al. reported a new Li super ionic conductor Li[subscript 10]GeP[subscript 2]S[subscript 12] (LGPS), which has the highest conductivity ever achieved among solid lithium electrolytes of 12 mS/cm at room temperature (comparable conductivity with liquid electrolytes) and outstanding electrochemical performance in Li batteries. |
first_indexed | 2024-09-23T10:12:03Z |
format | Article |
id | mit-1721.1/80290 |
institution | Massachusetts Institute of Technology |
language | en_US |
last_indexed | 2024-09-23T10:12:03Z |
publishDate | 2013 |
publisher | American Chemical Society (ACS) |
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spelling | mit-1721.1/802902022-09-30T19:33:51Z First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material Mo, Yifei Ong, Shyue Ping Ceder, Gerbrand Massachusetts Institute of Technology. Department of Materials Science and Engineering Ceder, Gerbrand Mo, Yifei Ong, Shyue Ping Ceder, Gerbrand The continued drive for high performance lithium batteries has imposed stricter requirements on the electrolyte materials. Solid electrolytes comprising lithium super ionic conductor materials exhibit good safety and stability and are promising to replace current organic liquid electrolytes. One major limitation in the application of Li-ion conductors is that their typical conductivity is less than 10[superscript −4] S/cm at room temperature. Recently, Kamaya et al. reported a new Li super ionic conductor Li[subscript 10]GeP[subscript 2]S[subscript 12] (LGPS), which has the highest conductivity ever achieved among solid lithium electrolytes of 12 mS/cm at room temperature (comparable conductivity with liquid electrolytes) and outstanding electrochemical performance in Li batteries. Samsung Advanced Institute of Technology 2013-08-26T21:09:47Z 2013-08-26T21:09:47Z 2011-12 2011-12 Article http://purl.org/eprint/type/JournalArticle 0897-4756 1520-5002 http://hdl.handle.net/1721.1/80290 Mo, Yifei, Shyue Ping Ong, and Gerbrand Ceder. “First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material.” Chemistry of Materials 24, no. 1 (January 10, 2012): 15-17. https://orcid.org/0000-0002-8162-4629 en_US http://dx.doi.org/10.1021/cm203303y Chemistry of Materials Creative Commons Attribution-Noncommercial-Share Alike 3.0 http://creativecommons.org/licenses/by-nc-sa/3.0/ application/pdf American Chemical Society (ACS) Prof. Ceder via Angie Locknar |
spellingShingle | Mo, Yifei Ong, Shyue Ping Ceder, Gerbrand First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material |
title | First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material |
title_full | First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material |
title_fullStr | First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material |
title_full_unstemmed | First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material |
title_short | First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material |
title_sort | first principles study of the li subscript 10 gep subscript 2 s subscript 12 lithium super ionic conductor material |
url | http://hdl.handle.net/1721.1/80290 https://orcid.org/0000-0002-8162-4629 |
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