Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material
We investigated the structural stability and electrochemical properties of LiMnBO3 in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on monoclinic LiMnBO[subscript 3] . In contrast to the negligible Li-storage capacity in the hexago...
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| Format: | Article |
| Language: | en_US |
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The Electrochemical Society
2013
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| Online Access: | http://hdl.handle.net/1721.1/80867 https://orcid.org/0000-0001-9999-6853 |
| _version_ | 1826210026967007232 |
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| author | Kim, Jae Chul Kang, Byoungwoo Hautier, Geoffroy Jain, Anubhav Ceder, Gerbrand Moore, Charles Jacob |
| author2 | Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science |
| author_facet | Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science Kim, Jae Chul Kang, Byoungwoo Hautier, Geoffroy Jain, Anubhav Ceder, Gerbrand Moore, Charles Jacob |
| author_sort | Kim, Jae Chul |
| collection | MIT |
| description | We investigated the structural stability and electrochemical properties of LiMnBO3 in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on monoclinic LiMnBO[subscript 3] . In contrast to the negligible Li-storage capacity in the hexagonal LiMnBO[subscript 3] , a second cycle discharge capacity of 100mAh/g was achieved in the monoclinic LiMnBO[subscript 3] , with good capacity retention over multiple cycles. Elevated temperature cycling indicates that the capacity of monoclinic LiMnBO[subscript 3] is kinetically limited, and further improvement may be expected by addressing the Li ion and/or electron transport limitations. |
| first_indexed | 2024-09-23T14:40:08Z |
| format | Article |
| id | mit-1721.1/80867 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T14:40:08Z |
| publishDate | 2013 |
| publisher | The Electrochemical Society |
| record_format | dspace |
| spelling | mit-1721.1/808672022-09-29T10:05:13Z Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material Kim, Jae Chul Kang, Byoungwoo Hautier, Geoffroy Jain, Anubhav Ceder, Gerbrand Moore, Charles Jacob Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science Massachusetts Institute of Technology. Department of Materials Science and Engineering Kim, Jae Chul Moore, Charles Jacob Kang, Byoungwoo Hautier, Geoffroy Jain, Anubhav Ceder, Gerbrand We investigated the structural stability and electrochemical properties of LiMnBO3 in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on monoclinic LiMnBO[subscript 3] . In contrast to the negligible Li-storage capacity in the hexagonal LiMnBO[subscript 3] , a second cycle discharge capacity of 100mAh/g was achieved in the monoclinic LiMnBO[subscript 3] , with good capacity retention over multiple cycles. Elevated temperature cycling indicates that the capacity of monoclinic LiMnBO[subscript 3] is kinetically limited, and further improvement may be expected by addressing the Li ion and/or electron transport limitations. United States. Dept. of Energy. Batteries for Advanced Transportation Technologies (BATT) Program (Contract DE-AC02-05CH11231) Robert Bosch Corporation Umicore Specialty Oxides and Chemicals National Science Foundation (U.S.) (Teragrid) (Grant TG-DMR970008S) 2013-09-23T16:12:21Z 2013-09-23T16:12:21Z 2011-01 2010-12 Article http://purl.org/eprint/type/JournalArticle 00134651 1945-7111 http://hdl.handle.net/1721.1/80867 Kim, Jae Chul, Charles J. Moore, Byoungwoo Kang, Geoffroy Hautier, Anubhav Jain, and Gerbrand Ceder. Synthesis and Electrochemical Properties of Monoclinic LiMnBO[sub 3] as a Li Intercalation Material. Journal of The Electrochemical Society 158, no. 3 (2011): A309. © 2011 ECS - The Electrochemical Society https://orcid.org/0000-0001-9999-6853 en_US http://dx.doi.org/10.1149/1.3536532 Journal of The Electrochemical Society Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf The Electrochemical Society MIT web domain |
| spellingShingle | Kim, Jae Chul Kang, Byoungwoo Hautier, Geoffroy Jain, Anubhav Ceder, Gerbrand Moore, Charles Jacob Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material |
| title | Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material |
| title_full | Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material |
| title_fullStr | Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material |
| title_full_unstemmed | Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material |
| title_short | Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material |
| title_sort | synthesis and electrochemical properties of monoclinic limnbo subscript 3 as a li intercalation material |
| url | http://hdl.handle.net/1721.1/80867 https://orcid.org/0000-0001-9999-6853 |
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