Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives

An intramolecular enantioselective metal-catalyzed dearomatization reaction is described. This procedure allows the dearomatization of naphthalene derivatives through an electrophilic aromatic substitution-type reaction on a Pd(II) intermediate. The high yields and enantioselectivities achieved make...

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Bibliographic Details
Main Authors: Kessler, Florian, Garcia-Fortanet, Jorge, Buchwald, Stephen Leffler
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2013
Online Access:http://hdl.handle.net/1721.1/82099
https://orcid.org/0000-0003-3875-4775