Characterization of a Peroxodiiron(III) Intermediate in the T201S Variant of Toluene/o-Xylene Monooxygenase Hydroxylase from Pseudomonas sp. OX1

Characterization of a Peroxodiiron(III) Intermediate in the T201S Variant of Toluene/o-Xylene Monooxygenase Hydroxylase from Pseudomonas sp. OX1

We report the observation of a novel intermediate in the reaction of a reduced toluene/o-xylene monooxygenase hydroxylase (ToMOH[subscript red]) T201S variant, in the presence of a regulatory protein (ToMOD), with dioxygen. This species is the first oxygenated intermediate with an optical band in an...

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Bibliografiske detaljer
Main Authors:	Song, Woon Ju, Behan, Rachel K., Naik, Sunil G., Huynh, Boi Hanh, Lippard, Stephen J.
Andre forfattere:	Massachusetts Institute of Technology. Department of Chemistry
Format:	Article
Sprog:	en_US
Udgivet:	American Chemical Society (ACS) 2013
Online adgang:	http://hdl.handle.net/1721.1/82137 https://orcid.org/0000-0002-2693-4982

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