Revisiting the Mechanism of Dioxygen Activation in Soluble Methane Monooxygenase from M. capsulatus (Bath): Evidence for a Multi-Step Proton-Dependent Reaction Pathway

Revisiting the Mechanism of Dioxygen Activation in Soluble Methane Monooxygenase from M. capsulatus (Bath): Evidence for a Multi-Step Proton-Dependent Reaction Pathway

Stopped-flow kinetic investigations of soluble methane monooxygenase (sMMO) from M. capsulatus (Bath) have clarified discrepancies that exist in the literature regarding several aspects of catalysis by this enzyme. The development of thorough kinetic analytical techniques has led to the discovery of...

书目详细资料
Main Authors:	Tinberg, Christine E., Lippard, Stephen J.
其他作者:	Massachusetts Institute of Technology. Department of Chemistry
格式:	文件
语言:	en_US
出版:	American Chemical Society (ACS) 2013
在线阅读:	http://hdl.handle.net/1721.1/82145 https://orcid.org/0000-0002-2693-4982

相似书籍

Dioxygen Activation in Soluble Methane Monooxygenase
由: Tinberg, Christine E., et al.
出版: (2012)

The methane monooxygenase gene cluster of methylococcus capsulatus(Bath)/
由: 496037 Stainthorpe, A. C., et al.

Structural and mutagenesis studies of soluble methane monooxygenase reductase from Methylococcus capsulatus (Bath)
由: Chatwood, Lisa L., 1979-
出版: (2005)

Electron transfer and protein engineering studies of the soluble methane monooxygenase from Methylococcus capsulatus (Bath)
由: Blazyk, Jessica L. (Jessica Lee), 1974-
出版: (2005)

Mechanistic and physical studies of methane monooxygenase from Methylococcus capsulatus (Bath)
由: Liu, Katherine E., 1967-
出版: (2006)

Oxidation Reactions Performed by Soluble Methane Monooxygenase Hydroxylase Intermediates H[subscript peroxo] and Q Proceed by Distinct Mechanisms
由: Tinberg, Christine E., et al.
出版: (2011)

Insights into the different dioxygen activation pathways of methane and toluene monooxygenase hydroxylases
由: Bochevarov, Arteum D., et al.
出版: (2012)

Structural studies of the hydroxylase component of methane monooxygenase from methyloccous capsulatus
由: Rosenzweig, Amy Claire
出版: (2005)

Electron Transfer Control in Soluble Methane Monooxygenase
由: Wang, Weixue, et al.
出版: (2015)

Carboxylate as the Protonation Site in (Peroxo)diiron(III) Model Complexes of Soluble Methane Monooxygenase and Related Diiron Proteins
由: Do, Loi Hung, et al.
出版: (2011)

Active Site Threonine Facilitates Proton Transfer during Dioxygen Activation at the Diiron Center of Toluene/o-Xylene Monooxygenase Hydroxylase
由: Song, Woon Ju, et al.
出版: (2011)

Bioinorganic hydrocarbon oxidation : mechanistic and kinetic studies of the soluble methane monooxygenase from Methylococcus capsulates (bath)
由: Valentine, Ann M. (Ann Margaret), 1971-
出版: (2010)

Studies of the soluble methane monooxygenase : heterologous expression and reactions with nitric oxide
由: Coufal, David E. (David Ernest), 1969-
出版: (2014)

Diiron Oxidation State Control of Substrate Access to the Active Site of Soluble Methane Monooxygenase Mediated by the Regulatory Component
由: Wang, Weixue, et al.
出版: (2015)

Multiple Roles of Component Proteins in Bacterial Multicomponent Monooxygenases: Phenol Hydroxylase and Toluene/o-Xylene Monooxygenase from Pseudomonas sp. OX1
由: Tinberg, Christine E., et al.
出版: (2012)

Exploring the reactivity of bacterial multicomponent monooxygenases
由: Tinberg, Christine Elaine
出版: (2011)

Fractionation of the Methane Isotopologues ¹³CH₄, ¹²CH₃D, and ¹³CH₃D During Aerobic Oxidation of Methane by Methylococcus Capsulatus (Bath)
由: Wang, David T., et al.
出版: (2018)

Control of substrate access to the active site in methane monooxygenase
由: Lee, Seung Jae, et al.
出版: (2013)

Electrochemical Monitoring of Metabolic Activity of Methane/Methanol Conversing Methylococcus Capsulatus (Bath) Cells Based on Extracellular Electron Transfer
由: Kugako SUGIMOTO, et al.
出版: (2024-02-01)

Capturing methane with recombinant soluble methane monooxygenase and recombinant methyl‐coenzyme M reductase
由: Viviana Sanchez‐Torres, et al.
出版: (2024-08-01)

Structural and functional models for methane monooxygenase
由: Feng, Xudong
出版: (2005)

Dioxygen activation and substrate hydroxylation by the hydroxylase component of toluene/O-xylene monooxygenase from pseudomonas sporium OX1
由: Murray, Leslie Justin
出版: (2008)

Overexpression of native carbonic anhydrases increases carbon conversion efficiency in the methanotrophic biocatalyst Methylococcus capsulatus Bath
由: Spencer A. Lee, et al.
出版: (2024-09-01)

Mechanistic Studies of Reactions of Peroxodiiron(III) Intermediates in T201 Variants of Toluene/o-Xylene Monooxygenase Hydroxylase
由: Lippard, Stephen J., et al.
出版: (2012)

Electrochemistry of soluble methane monooxygenase on a modified gold electrode : implications for chemical sensing in natural waters
由: Chuang, Janet Duanping
出版: (2006)

Bacterial Conjugation in Rhodobacter capsulatus
由: Molly Leung, et al.
出版: (2013-07-01)

Component Interactions and Electron Transfer in Toluene/o-Xylene Monooxygenase
由: Liang, Alexandria D, et al.
出版: (2017)

Expression of particulate methane monooxygenase (pMMO) proteins in plants for methane detoxification
由: Spatola Rossi, T
出版: (2022)

Can <i>Methylococcus capsulatus</i> Revolutionize Methane Capture and Utilization for Sustainable Energy Production?
由: Adenike A. Akinsemolu, et al.
出版: (2024-09-01)

Mechanistic studies of electron transfer, complex formation, C-H bond activation, and product binding in soluble methane monooxygenase
由: Kopp, Daniel Arthur
出版: (2005)

A rationally designed miniature of soluble methane monooxygenase enables rapid and high-yield methanol production in Escherichia coli
由: Yeonhwa Yu, et al.
出版: (2024-05-01)

Tracking a defined route for O2 migration in a dioxygen-activating diiron enzyme
由: Song, Woon Ju, et al.
出版: (2012)

Coupling Oxygen Consumption with Hydrocarbon Oxidation in Bacterial Multicomponent Monooxygenases
由: Wang, Weixue, et al.
出版: (2017)

A Flexible Glutamine Regulates the Catalytic Activity of Toluene o-Xylene Monooxygenase
由: Wrobel, Alexandra T., et al.
出版: (2015)

Single Turnover Reveals Oxygenated Intermediates in Toluene/o-Xylene Monooxygenase in the Presence of the Native Redox Partners
由: Liang, Alexandria D, et al.
出版: (2017)

Construction of Chromosomal In-Frame Deletion Mutants in Rhodobacter capsulatus
由: Molly Leung, et al.
出版: (2013-02-01)

Rhodobacter capsulatus Gene Transfer Agent Transduction Assay
由: Molly Leung, et al.
出版: (2013-02-01)

Dioxygen activation and homogeneous catalytic oxidation/
由: Simandi, L. I., et al.
出版: (1991)

The Adsorption Isobar of Dioxygen on Rhodium Powders
由: Yung-Sheng Ho, et al.
出版: (1990-03-01)

Dioxygen controls the nitrosylation reactions of a protein-bound [4Fe4S] cluster
由: Grabarczyk, D, et al.
出版: (2019)