Highly Z-Selective Metathesis Homocoupling of Terminal Olefins
Mo and W MonoAryloxide-Pyrrolide (MAP) olefin metathesis catalysts can couple terminal olefins to give as high as >98% Z-products in moderate to high yields with as little as 0.2% catalyst. Results are reported for 1-hexene, 1-octene, allylbenzene, allyltrimethylsilane, methyl-10-undecenoate, met...
Main Authors: | Jiang, Annie J., Zhao, Yu, Hoveyda, Amir H., Schrock, Richard Royce |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2013
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Online Access: | http://hdl.handle.net/1721.1/82550 https://orcid.org/0000-0001-5827-3552 |
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