Chain-Growth Polymerization of 2-Chlorothiophenes Promoted by Lewis Acids
Lewis acids promote the polymerization of several 2-chloroalkylenedioxythiophenes, providing high-molecular-weight conjugated polymers. The proposed mechanism is a cationic chain-growth polymerization, as confirmed by end-capping reactions and a linear correlation of molecular weight with percent co...
Main Authors: | Bonillo Fernandez, Baltasar, Swager, Timothy Manning |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2014
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Online Access: | http://hdl.handle.net/1721.1/84605 |
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