Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature

The deformation of metallic glasses involves two competing processes: a disordering process involving dilatation, free volume accumulation, and softening, and a relaxation process involving diffusional ordering and densification. For metallic glasses at room temperature and under uniaxial loading, d...

Full description

Bibliographic Details
Main Authors: Wang, Z. T., Pan, J., Li, Y., Schuh, Christopher A.
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering
Format: Article
Language:en_US
Published: American Physical Society 2014
Online Access:http://hdl.handle.net/1721.1/84981
https://orcid.org/0000-0001-9856-2682
_version_ 1826208692867956736
author Wang, Z. T.
Pan, J.
Li, Y.
Schuh, Christopher A.
author2 Massachusetts Institute of Technology. Department of Materials Science and Engineering
author_facet Massachusetts Institute of Technology. Department of Materials Science and Engineering
Wang, Z. T.
Pan, J.
Li, Y.
Schuh, Christopher A.
author_sort Wang, Z. T.
collection MIT
description The deformation of metallic glasses involves two competing processes: a disordering process involving dilatation, free volume accumulation, and softening, and a relaxation process involving diffusional ordering and densification. For metallic glasses at room temperature and under uniaxial loading, disordering usually dominates, and the glass can fail catastrophically as the softening process runs away in a localized mode. Here we demonstrate conditions where the opposite, unexpected, situation occurs: the densifying process dominates, resulting in stable plastic deformation and work hardening at room temperature. We report densification and hardening during deformation in a Zr-based glass under multiaxial loading, in a notched tensile geometry. The effect is driven by stress-enhanced diffusional relaxation, and is attended by a reduction in exothermic heat and hardening signatures similar to those observed in the classical thermal relaxation of glasses. The result is significant, stable, plastic, extensional flow in metallic glasses, which suggest a possibility of designing tough glasses based on their flow properties.
first_indexed 2024-09-23T14:09:46Z
format Article
id mit-1721.1/84981
institution Massachusetts Institute of Technology
language en_US
last_indexed 2024-09-23T14:09:46Z
publishDate 2014
publisher American Physical Society
record_format dspace
spelling mit-1721.1/849812022-09-28T18:57:41Z Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature Wang, Z. T. Pan, J. Li, Y. Schuh, Christopher A. Massachusetts Institute of Technology. Department of Materials Science and Engineering Schuh, Christopher A. The deformation of metallic glasses involves two competing processes: a disordering process involving dilatation, free volume accumulation, and softening, and a relaxation process involving diffusional ordering and densification. For metallic glasses at room temperature and under uniaxial loading, disordering usually dominates, and the glass can fail catastrophically as the softening process runs away in a localized mode. Here we demonstrate conditions where the opposite, unexpected, situation occurs: the densifying process dominates, resulting in stable plastic deformation and work hardening at room temperature. We report densification and hardening during deformation in a Zr-based glass under multiaxial loading, in a notched tensile geometry. The effect is driven by stress-enhanced diffusional relaxation, and is attended by a reduction in exothermic heat and hardening signatures similar to those observed in the classical thermal relaxation of glasses. The result is significant, stable, plastic, extensional flow in metallic glasses, which suggest a possibility of designing tough glasses based on their flow properties. United States. Defense Threat Reduction Agency (Grant HDTRA-11-1-0062) 2014-02-18T17:33:23Z 2014-02-18T17:33:23Z 2013-09 2013-07 Article http://purl.org/eprint/type/JournalArticle 0031-9007 1079-7114 http://hdl.handle.net/1721.1/84981 Wang, Z. T., J. Pan, Y. Li, and C. A. Schuh. “Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature.” Physical Review Letters 111, no. 13 (September 2013). © 2013 American Physical Society https://orcid.org/0000-0001-9856-2682 en_US http://dx.doi.org/10.1103/PhysRevLett.111.135504 Physical Review Letters Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Physical Society American Physical Society
spellingShingle Wang, Z. T.
Pan, J.
Li, Y.
Schuh, Christopher A.
Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature
title Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature
title_full Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature
title_fullStr Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature
title_full_unstemmed Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature
title_short Densification and Strain Hardening of a Metallic Glass under Tension at Room Temperature
title_sort densification and strain hardening of a metallic glass under tension at room temperature
url http://hdl.handle.net/1721.1/84981
https://orcid.org/0000-0001-9856-2682
work_keys_str_mv AT wangzt densificationandstrainhardeningofametallicglassundertensionatroomtemperature
AT panj densificationandstrainhardeningofametallicglassundertensionatroomtemperature
AT liy densificationandstrainhardeningofametallicglassundertensionatroomtemperature
AT schuhchristophera densificationandstrainhardeningofametallicglassundertensionatroomtemperature