A facile route for 3D aerogels from nanostructured 1D and 2D materials

Aerogels have numerous applications due to their high surface area and low densities. However, creating aerogels from a large variety of materials has remained an outstanding challenge. Here, we report a new methodology to enable aerogel production with a wide range of materials. The method is based...

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Main Authors: Jung, Sung Mi, Jung, Hyun Young, Dresselhaus, Mildred, Jung, Yung Joon, Kong, Jing
Other Authors: Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Format: Article
Language:en_US
Published: Nature Publishing Group 2014
Online Access:http://hdl.handle.net/1721.1/87115
https://orcid.org/0000-0001-8492-2261
https://orcid.org/0000-0003-0551-1208
https://orcid.org/0000-0002-9950-1387
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author Jung, Sung Mi
Jung, Hyun Young
Dresselhaus, Mildred
Jung, Yung Joon
Kong, Jing
author2 Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
author_facet Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Jung, Sung Mi
Jung, Hyun Young
Dresselhaus, Mildred
Jung, Yung Joon
Kong, Jing
author_sort Jung, Sung Mi
collection MIT
description Aerogels have numerous applications due to their high surface area and low densities. However, creating aerogels from a large variety of materials has remained an outstanding challenge. Here, we report a new methodology to enable aerogel production with a wide range of materials. The method is based on the assembly of anisotropic nano-objects (one-dimensional (1D) nanotubes, nanowires, or two-dimensional (2D) nanosheets) into a cross-linking network from their colloidal suspensions at the transition from the semi-dilute to the isotropic concentrated regime. The resultant aerogels have highly porous and ultrafine three-dimensional (3D) networks consisting of 1D (Ag, Si, MnO2, single-walled carbon nanotubes (SWNTs)) and 2D materials (MoS2, graphene, h-BN) with high surface areas, low densities, and high electrical conductivities. This method opens up a facile route for aerogel production with a wide variety of materials and tremendous opportunities for bio-scaffold, energy storage, thermoelectric, catalysis, and hydrogen storage applications.
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spelling mit-1721.1/871152024-03-18T20:53:34Z A facile route for 3D aerogels from nanostructured 1D and 2D materials Jung, Sung Mi Jung, Hyun Young Dresselhaus, Mildred Jung, Yung Joon Kong, Jing Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science Massachusetts Institute of Technology. Department of Mechanical Engineering Massachusetts Institute of Technology. Department of Physics Jung, Sung Mi Dresselhaus, Mildred Kong, Jing Aerogels have numerous applications due to their high surface area and low densities. However, creating aerogels from a large variety of materials has remained an outstanding challenge. Here, we report a new methodology to enable aerogel production with a wide range of materials. The method is based on the assembly of anisotropic nano-objects (one-dimensional (1D) nanotubes, nanowires, or two-dimensional (2D) nanosheets) into a cross-linking network from their colloidal suspensions at the transition from the semi-dilute to the isotropic concentrated regime. The resultant aerogels have highly porous and ultrafine three-dimensional (3D) networks consisting of 1D (Ag, Si, MnO2, single-walled carbon nanotubes (SWNTs)) and 2D materials (MoS2, graphene, h-BN) with high surface areas, low densities, and high electrical conductivities. This method opens up a facile route for aerogel production with a wide variety of materials and tremendous opportunities for bio-scaffold, energy storage, thermoelectric, catalysis, and hydrogen storage applications. National Science Foundation (U.S.) (award number NSF DMR 0845358) MIT Energy Initiative Douglas Spreng '65 Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies 2014-05-23T13:42:50Z 2014-05-23T13:42:50Z 2012-11 2012-06 Article http://purl.org/eprint/type/JournalArticle 2045-2322 http://hdl.handle.net/1721.1/87115 Jung, Sung Mi, Hyun Young Jung, Mildred S. Dresselhaus, Yung Joon Jung, and Jing Kong. “A Facile Route for 3D Aerogels from Nanostructured 1D and 2D Materials.” Sci. Rep. 2 (November 14, 2012). https://orcid.org/0000-0001-8492-2261 https://orcid.org/0000-0003-0551-1208 https://orcid.org/0000-0002-9950-1387 en_US http://dx.doi.org/10.1038/srep00849 Scientific Reports Creative Commons Attribution-NonCommercial-No Derivative Works 3.0 Unported License http://creativecommons.org/licenses/by-nc-nd/3.0/ application/pdf Nature Publishing Group Scientific Reports
spellingShingle Jung, Sung Mi
Jung, Hyun Young
Dresselhaus, Mildred
Jung, Yung Joon
Kong, Jing
A facile route for 3D aerogels from nanostructured 1D and 2D materials
title A facile route for 3D aerogels from nanostructured 1D and 2D materials
title_full A facile route for 3D aerogels from nanostructured 1D and 2D materials
title_fullStr A facile route for 3D aerogels from nanostructured 1D and 2D materials
title_full_unstemmed A facile route for 3D aerogels from nanostructured 1D and 2D materials
title_short A facile route for 3D aerogels from nanostructured 1D and 2D materials
title_sort facile route for 3d aerogels from nanostructured 1d and 2d materials
url http://hdl.handle.net/1721.1/87115
https://orcid.org/0000-0001-8492-2261
https://orcid.org/0000-0003-0551-1208
https://orcid.org/0000-0002-9950-1387
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