Facile synthesis of mononuclear early transition-metal complexes of κ[superscript 3]cyclo-tetrametaphosphate ([P[subscript 4]O[subscript 12]][superscript 4−]) and cyclo-trimetaphosphate ([P[subscript 3]O[subscript 9]][superscript 3−])

Facile synthesis of mononuclear early transition-metal complexes of κ[superscript 3]cyclo-tetrametaphosphate ([P[subscript 4]O[subscript 12]][superscript 4−]) and cyclo-trimetaphosphate ([P[subscript 3]O[subscript 9]][superscript 3−])

We herein report the preparation of several mononuclear-metaphosphate complexes using simple techniques and mild conditions with yields ranging from 56% to 78%. Treatment of cyclo-tetrametaphosphate ([TBA]4[P4O12]·5H2O, TBA = tetra-n-butylammonium) with various metal sources including (CH3CN)3Mo(CO)...

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Bibliographic Details
Main Authors:	Manna, Cesar M., Nassar, Mostafa Y., Tofan, Daniel, Chakarawet, Khetpakorn, Cummins, Christopher C.
Other Authors:	Massachusetts Institute of Technology. Department of Chemistry
Format:	Article
Language:	en_US
Published:	Royal Society of Chemistry 2014
Online Access:	http://hdl.handle.net/1721.1/90949 https://orcid.org/0000-0003-2568-3269

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