Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion
Thin films of bilayer poly(divinyl benzene) p(DVB)/poly(perfluorodecylacrylate) (p-PFDA) are synthesized via iCVD on steel and silicon substrates. Nanomechanical measurements reveal that the elastic modulus and hardness of the films are enhanced through the bilayer structure and that the adhesion of...
| Main Authors: | , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
Royal Society of Chemistry
2014
|
| Online Access: | http://hdl.handle.net/1721.1/91559 https://orcid.org/0000-0001-6127-1056 https://orcid.org/0000-0001-8323-2779 https://orcid.org/0000-0003-1365-9640 |
| _version_ | 1826204071014432768 |
|---|---|
| author | Sojoudi, Hossein McKinley, Gareth H. Gleason, Karen K. |
| author2 | Massachusetts Institute of Technology. Department of Chemical Engineering |
| author_facet | Massachusetts Institute of Technology. Department of Chemical Engineering Sojoudi, Hossein McKinley, Gareth H. Gleason, Karen K. |
| author_sort | Sojoudi, Hossein |
| collection | MIT |
| description | Thin films of bilayer poly(divinyl benzene) p(DVB)/poly(perfluorodecylacrylate) (p-PFDA) are synthesized via iCVD on steel and silicon substrates. Nanomechanical measurements reveal that the elastic modulus and hardness of the films are enhanced through the bilayer structure and that the adhesion of the films to the substrate is improved via in situ grafting mechanism. The strength of ice adhesion to the treated surfaces is reduced more than six-fold when the substrates are coated with these bilayer polymer networks. |
| first_indexed | 2024-09-23T12:48:27Z |
| format | Article |
| id | mit-1721.1/91559 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T12:48:27Z |
| publishDate | 2014 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | mit-1721.1/915592023-09-03T04:45:08Z Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion Sojoudi, Hossein McKinley, Gareth H. Gleason, Karen K. Massachusetts Institute of Technology. Department of Chemical Engineering Massachusetts Institute of Technology. Department of Mechanical Engineering Sojoudi, Hossein McKinley, Gareth H. Gleason, Karen K. Thin films of bilayer poly(divinyl benzene) p(DVB)/poly(perfluorodecylacrylate) (p-PFDA) are synthesized via iCVD on steel and silicon substrates. Nanomechanical measurements reveal that the elastic modulus and hardness of the films are enhanced through the bilayer structure and that the adhesion of the films to the substrate is improved via in situ grafting mechanism. The strength of ice adhesion to the treated surfaces is reduced more than six-fold when the substrates are coated with these bilayer polymer networks. Chevron-MIT Energy Initiative 2014-11-13T19:49:31Z 2014-11-13T19:49:31Z 2014-10 2014-08 Article http://purl.org/eprint/type/JournalArticle 2051-6347 2051-6355 http://hdl.handle.net/1721.1/91559 Sojoudi, Hossein, Gareth H. McKinley, and Karen K. Gleason. “Linker-Free Grafting of Fluorinated Polymeric Cross-Linked Network Bilayers for Durable Reduction of Ice Adhesion.” Mater. Horiz. (2014). https://orcid.org/0000-0001-6127-1056 https://orcid.org/0000-0001-8323-2779 https://orcid.org/0000-0003-1365-9640 en_US http://dx.doi.org/10.1039/c4mh00162a Materials Horizons Creative Commons Attribution https://creativecommons.org/licenses/by/3.0/ application/pdf Royal Society of Chemistry RSC |
| spellingShingle | Sojoudi, Hossein McKinley, Gareth H. Gleason, Karen K. Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion |
| title | Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion |
| title_full | Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion |
| title_fullStr | Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion |
| title_full_unstemmed | Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion |
| title_short | Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion |
| title_sort | linker free grafting of fluorinated polymeric cross linked network bilayers for durable reduction of ice adhesion |
| url | http://hdl.handle.net/1721.1/91559 https://orcid.org/0000-0001-6127-1056 https://orcid.org/0000-0001-8323-2779 https://orcid.org/0000-0003-1365-9640 |
| work_keys_str_mv | AT sojoudihossein linkerfreegraftingoffluorinatedpolymericcrosslinkednetworkbilayersfordurablereductionoficeadhesion AT mckinleygarethh linkerfreegraftingoffluorinatedpolymericcrosslinkednetworkbilayersfordurablereductionoficeadhesion AT gleasonkarenk linkerfreegraftingoffluorinatedpolymericcrosslinkednetworkbilayersfordurablereductionoficeadhesion |