Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides
An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product.
| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
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American Chemical Society (ACS)
2015
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| Online Access: | http://hdl.handle.net/1721.1/93917 https://orcid.org/0000-0003-3875-4775 |
| _version_ | 1811085646576484352 |
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| author | Yang, Yang Buchwald, Stephen Leffler |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Yang, Yang Buchwald, Stephen Leffler |
| author_sort | Yang, Yang |
| collection | MIT |
| description | An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product. |
| first_indexed | 2024-09-23T13:13:00Z |
| format | Article |
| id | mit-1721.1/93917 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T13:13:00Z |
| publishDate | 2015 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/939172022-09-28T12:40:00Z Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides Yang, Yang Buchwald, Stephen Leffler Massachusetts Institute of Technology. Department of Chemistry Yang, Yang Buchwald, Stephen Leffler An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product. National Institutes of Health (U.S.) (GM46059) 2015-02-06T20:06:40Z 2015-02-06T20:06:40Z 2013-07 2013-06 Article http://purl.org/eprint/type/JournalArticle 0002-7863 1520-5126 http://hdl.handle.net/1721.1/93917 Yang, Yang, and Stephen L. Buchwald. “Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides.” Journal of the American Chemical Society 135, no. 29 (July 24, 2013): 10642–10645. https://orcid.org/0000-0003-3875-4775 en_US http://dx.doi.org/10.1021/ja405950c Journal of the American Chemical Society Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) PMC |
| spellingShingle | Yang, Yang Buchwald, Stephen Leffler Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides |
| title | Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides |
| title_full | Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides |
| title_fullStr | Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides |
| title_full_unstemmed | Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides |
| title_short | Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides |
| title_sort | ligand controlled palladium catalyzed regiodivergent suzuki miyaura cross coupling of allylboronates and aryl halides |
| url | http://hdl.handle.net/1721.1/93917 https://orcid.org/0000-0003-3875-4775 |
| work_keys_str_mv | AT yangyang ligandcontrolledpalladiumcatalyzedregiodivergentsuzukimiyauracrosscouplingofallylboronatesandarylhalides AT buchwaldstephenleffler ligandcontrolledpalladiumcatalyzedregiodivergentsuzukimiyauracrosscouplingofallylboronatesandarylhalides |