Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates
A new air-stable nickel precatalyst for C–N cross-coupling is reported. The developed catalyst system displays a greatly improved substrate scope for C–N bond formation to include both a wide range of aryl and heteroaryl electrophiles and aryl, heteroaryl, and alkylamines. The catalyst system is als...
Main Authors: | Teverovskiy, Georgiy, Park, Nathaniel Hamilton, Buchwald, Stephen Leffler |
---|---|
Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2015
|
Online Access: | http://hdl.handle.net/1721.1/94344 https://orcid.org/0000-0002-3967-2483 https://orcid.org/0000-0003-3875-4775 |
Similar Items
-
Pd-Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics
by: Fors, Brett P., et al.
Published: (2013) -
Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
by: Shen, Xiaoqiang, et al.
Published: (2012) -
Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides
by: Watson, Donald A., et al.
Published: (2013) -
Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
by: Pan, Jun, et al.
Published: (2013) -
Enantioselective intermolecular Heck and reductive Heck reactions of aryl triflates, mesylates, and tosylates catalyzed by nickel
by: Huang, Xiaolei, et al.
Published: (2021)