Nickel-Catalyzed Mizoroki-Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products

Achieving high selectivity in the Heck reaction of electronically unbiased alkenes has been a longstanding challenge. Using a nickel-catalyzed cationic Heck reaction, we were able to achieve excellent selectivity for branched products (≥19:1 in all cases) over a wide range of aryl electrophiles and...

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Bibliographic Details
Main Authors: Tasker, Sarah Z., Gutierrez, Alicia C., Jamison, Timothy F., Tasker, Sarah Zinnen
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: Wiley-VCH Verlag GmbH & Co. 2015
Online Access:http://hdl.handle.net/1721.1/94650
https://orcid.org/0000-0003-2315-6983
https://orcid.org/0000-0002-8601-7799