Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products
Mononitrosyldiiron complexes having either an [Fe[superscript II]·{FeNO}[superscript 7]] or an [Fe[superscript III]·{FeNO}[superscript 7]] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical d...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
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American Chemical Society (ACS)
2015
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| Online Access: | http://hdl.handle.net/1721.1/95479 https://orcid.org/0000-0002-2693-4982 |
| _version_ | 1826216672850083840 |
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| author | Majumdar, Amit Lippard, Stephen J. |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Majumdar, Amit Lippard, Stephen J. |
| author_sort | Majumdar, Amit |
| collection | MIT |
| description | Mononitrosyldiiron complexes having either an [Fe[superscript II]·{FeNO}[superscript 7]] or an [Fe[superscript III]·{FeNO}[superscript 7]] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [Fe[superscript III]·{FeNO}[superscript 7]] are described. |
| first_indexed | 2024-09-23T16:51:35Z |
| format | Article |
| id | mit-1721.1/95479 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T16:51:35Z |
| publishDate | 2015 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/954792022-09-29T21:57:04Z Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products Majumdar, Amit Lippard, Stephen J. Massachusetts Institute of Technology. Department of Chemistry Lippard, Stephen J. Majumdar, Amit Mononitrosyldiiron complexes having either an [Fe[superscript II]·{FeNO}[superscript 7]] or an [Fe[superscript III]·{FeNO}[superscript 7]] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [Fe[superscript III]·{FeNO}[superscript 7]] are described. National Institute of General Medical Sciences (U.S.) (Grant GM 32114) 2015-02-24T16:01:32Z 2015-02-24T16:01:32Z 2013-11 2013-07 Article http://purl.org/eprint/type/JournalArticle 0020-1669 1520-510X http://hdl.handle.net/1721.1/95479 Majumdar, Amit, and Stephen J. Lippard. “Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products.” Inorg. Chem. 52, no. 23 (December 2, 2013): 13292–13294. https://orcid.org/0000-0002-2693-4982 en_US http://dx.doi.org/10.1021/ic4019508 Inorganic Chemistry Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) PMC |
| spellingShingle | Majumdar, Amit Lippard, Stephen J. Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products |
| title | Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products |
| title_full | Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products |
| title_fullStr | Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products |
| title_full_unstemmed | Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products |
| title_short | Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products |
| title_sort | non heme mononitrosyldiiron complexes importance of iron oxidation state in controlling the nature of the nitrosylated products |
| url | http://hdl.handle.net/1721.1/95479 https://orcid.org/0000-0002-2693-4982 |
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