Conversion between Doubly and Triply Carboxylate Bridged Bis(ethylzinc) Complexes and Formation of the (μ-Oxo)tetrazinc Carboxylate [Zn[subscript 4]O(Ar[superscript Tol]CO[subscript 2)[subscript 6]]

Conversion between Doubly and Triply Carboxylate Bridged Bis(ethylzinc) Complexes and Formation of the (μ-Oxo)tetrazinc Carboxylate [Zn[subscript 4]O(Ar[superscript Tol]CO[subscript 2)[subscript 6]]

Ethylzinc 2,6-bis(p-tolyl)benzoate converts between two forms in solution. Through NMR spectroscopic techniques and X-ray crystallography, the species in equilibrium were identified as [Zn[subscript 2](Ar[superscript Tol]CO[subscript 2])[subscript 2](Et)[subscript 2](THF)[subscript 2]] (1), [Zn[subs...

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Bibliographic Details
Main Authors:	Lippard, Stephen J., Minier, Mikael Antoine
Other Authors:	Massachusetts Institute of Technology. Department of Chemistry
Format:	Article
Language:	en_US
Published:	American Chemical Society (ACS) 2015
Online Access:	http://hdl.handle.net/1721.1/95742 https://orcid.org/0000-0002-2693-4982 https://orcid.org/0000-0002-8346-9570

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