The mechanics of strain-induced crystallization in poly(ethylene terephthalate)
Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1998.
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| Format: | Thesis |
| Language: | eng |
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Massachusetts Institute of Technology
2005
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| Online Access: | http://hdl.handle.net/1721.1/9597 |
| _version_ | 1811071901162799104 |
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| author | Llana, Patricia G. (Patricia Gracia), 1974- |
| author2 | Mary C. Boyce. |
| author_facet | Mary C. Boyce. Llana, Patricia G. (Patricia Gracia), 1974- |
| author_sort | Llana, Patricia G. (Patricia Gracia), 1974- |
| collection | MIT |
| description | Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1998. |
| first_indexed | 2024-09-23T08:57:45Z |
| format | Thesis |
| id | mit-1721.1/9597 |
| institution | Massachusetts Institute of Technology |
| language | eng |
| last_indexed | 2024-09-23T08:57:45Z |
| publishDate | 2005 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/95972020-08-18T13:00:31Z The mechanics of strain-induced crystallization in poly(ethylene terephthalate) Llana, Patricia G. (Patricia Gracia), 1974- Mary C. Boyce. Massachusetts Institute of Technology. Department of Mechanical Engineering Mechanical Engineering Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1998. Includes bibliographical references (p. 279-282). Poly( ethylene terephthalate) (PET) is a thermoplastic polymer found in numerous commercial applications. PET exhibits the capability of undergoing strain-induced crystallization during processing, the result of which is increased stiffness and hardness as well as better dimensional stability. An experimental study of the strain rate, strain state, and temperature dependencies of the stress-strain behavior of PET under large strain deformation was conducted over a wide range of strain rates (-0.005/s - 02.0/s) and temperatures (25 ° C - 105 ° C) and in both uniaxial and plane strain compression. The increase in crystallinity content with varying strain rate and temperature and for the two different states of strain that developed as a result of these deformation conditions was investigated using Differential Scanning Calorimetry (DSC). The nature and evolution of the crystallographic texture was studied using Wide Angle X-ray Diffraction (WAXD) measurements. The results of the mechanical tests, DSC and WAXD measurements indicated that straininduced crystallization does not occur in uniaxial compression at temperatures below the glass transition, however, a shift in the cold crystallization exotherm was observed. Alternatively, in plane strain compression at these temperatures for the fastest strain rates, DSC measurements indicated an increase in crystallinity. At temperatures near the glass transition in uniaxial compression, DSC measurements indicated an increase in crystallinity, whereas WAXD measurements indicated only molecular orientation. In plane strain compression, however, both DSC and WAXD measurements indicated an increase in crystallinity. At temperatures above the glass transition temperature, both DSC and WAXD indicated an increase in crystallinity in both uniaxial and plane strain compression. It was found that the percent crystallinity increased with increasing strain rate and decreasing temperature and that the crystallographic texture that develops is dependent on the state of strain. A constitutive model that predicts the strain rate, strain state and temperature dependence of PET was developed that captures these dependencies very well. by Patricia G. Llana. S.M. 2005-08-19T18:48:53Z 2005-08-19T18:48:53Z 1998 1998 Thesis http://hdl.handle.net/1721.1/9597 42192765 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 282 p. 11965143 bytes 11964897 bytes application/pdf application/pdf application/pdf Massachusetts Institute of Technology |
| spellingShingle | Mechanical Engineering Llana, Patricia G. (Patricia Gracia), 1974- The mechanics of strain-induced crystallization in poly(ethylene terephthalate) |
| title | The mechanics of strain-induced crystallization in poly(ethylene terephthalate) |
| title_full | The mechanics of strain-induced crystallization in poly(ethylene terephthalate) |
| title_fullStr | The mechanics of strain-induced crystallization in poly(ethylene terephthalate) |
| title_full_unstemmed | The mechanics of strain-induced crystallization in poly(ethylene terephthalate) |
| title_short | The mechanics of strain-induced crystallization in poly(ethylene terephthalate) |
| title_sort | mechanics of strain induced crystallization in poly ethylene terephthalate |
| topic | Mechanical Engineering |
| url | http://hdl.handle.net/1721.1/9597 |
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