A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction

With the advent of efficient high-bandgap metal-halide perovskite photovoltaics, an opportunity exists to make perovskite/silicon tandem solar cells. We fabricate a monolithic tandem by developing a silicon-based interband tunnel junction that facilitates majority-carrier charge recombination betwee...

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Main Authors: Mailoa, Jonathan P., Bailie, Colin D., Johlin, Eric Carl, Hoke, Eric T., Akey, Austin J., Nguyen, William H., McGehee, Michael D., Buonassisi, Tonio
Other Authors: Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Format: Article
Language:en_US
Published: American Institute of Physics (AIP) 2015
Online Access:http://hdl.handle.net/1721.1/96207
https://orcid.org/0000-0003-2239-6192
https://orcid.org/0000-0001-8345-4937
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author Mailoa, Jonathan P.
Bailie, Colin D.
Johlin, Eric Carl
Hoke, Eric T.
Akey, Austin J.
Nguyen, William H.
McGehee, Michael D.
Buonassisi, Tonio
author2 Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
author_facet Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Mailoa, Jonathan P.
Bailie, Colin D.
Johlin, Eric Carl
Hoke, Eric T.
Akey, Austin J.
Nguyen, William H.
McGehee, Michael D.
Buonassisi, Tonio
author_sort Mailoa, Jonathan P.
collection MIT
description With the advent of efficient high-bandgap metal-halide perovskite photovoltaics, an opportunity exists to make perovskite/silicon tandem solar cells. We fabricate a monolithic tandem by developing a silicon-based interband tunnel junction that facilitates majority-carrier charge recombination between the perovskite and silicon sub-cells. We demonstrate a 1 cm[superscript 2] 2-terminal monolithic perovskite/silicon multijunction solar cell with a V [subscript OC] as high as 1.65 V. We achieve a stable 13.7% power conversion efficiency with the perovskite as the current-limiting sub-cell, and identify key challenges for this device architecture to reach efficiencies over 25%.
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spelling mit-1721.1/962072022-10-01T08:38:37Z A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction Mailoa, Jonathan P. Bailie, Colin D. Johlin, Eric Carl Hoke, Eric T. Akey, Austin J. Nguyen, William H. McGehee, Michael D. Buonassisi, Tonio Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science Massachusetts Institute of Technology. Department of Mechanical Engineering Massachusetts Institute of Technology. Laboratory for Manufacturing and Productivity Mailoa, Jonathan P. Johlin, Eric Carl Akey, Austin J. Buonassisi, Tonio With the advent of efficient high-bandgap metal-halide perovskite photovoltaics, an opportunity exists to make perovskite/silicon tandem solar cells. We fabricate a monolithic tandem by developing a silicon-based interband tunnel junction that facilitates majority-carrier charge recombination between the perovskite and silicon sub-cells. We demonstrate a 1 cm[superscript 2] 2-terminal monolithic perovskite/silicon multijunction solar cell with a V [subscript OC] as high as 1.65 V. We achieve a stable 13.7% power conversion efficiency with the perovskite as the current-limiting sub-cell, and identify key challenges for this device architecture to reach efficiencies over 25%. Bay Area Photovoltaic Consortium (Contract DE-EE0004946) United States. Dept. of Energy (Contract DE-EE0006707) 2015-03-27T15:09:07Z 2015-03-27T15:09:07Z 2015-03 2015-02 Article http://purl.org/eprint/type/JournalArticle 0003-6951 1077-3118 http://hdl.handle.net/1721.1/96207 Mailoa, Jonathan P. et al. “A 2-Terminal Perovskite/silicon Multijunction Solar Cell Enabled by a Silicon Tunnel Junction.” Applied Physics Letters 106.12 (2015): 121105. © 2015 AIP Publishing LLC https://orcid.org/0000-0003-2239-6192 https://orcid.org/0000-0001-8345-4937 en_US http://dx.doi.org/10.1063/1.4914179 Applied Physics Letters Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Institute of Physics (AIP) Mailoa
spellingShingle Mailoa, Jonathan P.
Bailie, Colin D.
Johlin, Eric Carl
Hoke, Eric T.
Akey, Austin J.
Nguyen, William H.
McGehee, Michael D.
Buonassisi, Tonio
A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
title A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
title_full A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
title_fullStr A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
title_full_unstemmed A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
title_short A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
title_sort 2 terminal perovskite silicon multijunction solar cell enabled by a silicon tunnel junction
url http://hdl.handle.net/1721.1/96207
https://orcid.org/0000-0003-2239-6192
https://orcid.org/0000-0001-8345-4937
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