Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing

The anticipated increase in demand for potassium fertilizers and alumina from developing nations experiencing a high-rate of population growth brings a global sustainability concern. Most of these countries do not have economically viable resources for both commodities; and the environmental footpri...

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Main Authors: Skorina, Taisiya, Allanore, Antoine
Other Authors: Massachusetts Institute of Technology. Materials Processing Center
Format: Article
Language:en_US
Published: Royal Society of Chemistry 2015
Online Access:http://hdl.handle.net/1721.1/96725
https://orcid.org/0000-0002-2594-0264
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author Skorina, Taisiya
Allanore, Antoine
author2 Massachusetts Institute of Technology. Materials Processing Center
author_facet Massachusetts Institute of Technology. Materials Processing Center
Skorina, Taisiya
Allanore, Antoine
author_sort Skorina, Taisiya
collection MIT
description The anticipated increase in demand for potassium fertilizers and alumina from developing nations experiencing a high-rate of population growth brings a global sustainability concern. Most of these countries do not have economically viable resources for both commodities; and the environmental footprint of existing technologies may compromise local ecosystems. Alternatives, both in terms of resources and extraction technologies, are therefore needed. Aqueous alteration of potassium-bearing aluminosilicate minerals has been proposed as an alternative to both traditional K-fertilization and alumina production. This work discusses the mechanism of aqueous alteration of aluminosilicate minerals, and the chemical processes that have been proposed to date. Although extensive studies are found in the fields of geochemistry and materials chemistry, their results have rarely been analysed and engineered to allow a proper control and design of chemical processing. The review suggests that such a multi-disciplinary approach is required to enable new technologies that both comply with green chemistry principles and are economically viable.
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spelling mit-1721.1/967252022-10-02T07:13:38Z Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing Skorina, Taisiya Allanore, Antoine Massachusetts Institute of Technology. Materials Processing Center Massachusetts Institute of Technology. Department of Materials Science and Engineering Skorina, Taisiya Allanore, Antoine The anticipated increase in demand for potassium fertilizers and alumina from developing nations experiencing a high-rate of population growth brings a global sustainability concern. Most of these countries do not have economically viable resources for both commodities; and the environmental footprint of existing technologies may compromise local ecosystems. Alternatives, both in terms of resources and extraction technologies, are therefore needed. Aqueous alteration of potassium-bearing aluminosilicate minerals has been proposed as an alternative to both traditional K-fertilization and alumina production. This work discusses the mechanism of aqueous alteration of aluminosilicate minerals, and the chemical processes that have been proposed to date. Although extensive studies are found in the fields of geochemistry and materials chemistry, their results have rarely been analysed and engineered to allow a proper control and design of chemical processing. The review suggests that such a multi-disciplinary approach is required to enable new technologies that both comply with green chemistry principles and are economically viable. 2015-04-23T13:48:38Z 2015-04-23T13:48:38Z 2015-03 2014-10 Article http://purl.org/eprint/type/JournalArticle 1463-9262 1463-9270 http://hdl.handle.net/1721.1/96725 Skorina, Taisiya, and Antoine Allanore. “Aqueous Alteration of Potassium-Bearing Aluminosilicate Minerals: From Mechanism to Processing.” Green Chem. 17, no. 4 (2015): 2123–2136. © 2015 Royal Society of Chemistry https://orcid.org/0000-0002-2594-0264 en_US http://dx.doi.org/10.1039/c4gc02084g Green Chemistry Creative Commons Attribution http://creativecommons.org/licenses/by/3.0/ application/pdf Royal Society of Chemistry RSC
spellingShingle Skorina, Taisiya
Allanore, Antoine
Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing
title Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing
title_full Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing
title_fullStr Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing
title_full_unstemmed Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing
title_short Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing
title_sort aqueous alteration of potassium bearing aluminosilicate minerals from mechanism to processing
url http://hdl.handle.net/1721.1/96725
https://orcid.org/0000-0002-2594-0264
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