N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C–C and C–N Cross-Couplings
A series of phosphine-ligated palladium precatalysts based on N-methyl- and N-phenyl-2-aminobiphenyl have been developed. Substitution at the nitrogen center prevents the presence of traces of aminobiphenyls that contain a free −NH[subscript 2] group from contaminating cross-coupling products. These...
Main Authors: | Bruno, Nicholas C., Niljianskul, Nootaree, Buchwald, Stephen Leffler |
---|---|
Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
2015
|
Online Access: | http://hdl.handle.net/1721.1/97471 https://orcid.org/0000-0003-3875-4775 |
Similar Items
-
Design and preparation of new palladium precatalysts for C–C and C–N cross-coupling reactions
by: Bruno, Nicholas C., et al.
Published: (2015) -
The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C–N Cross-Coupling
by: Liu, Richard, et al.
Published: (2022) -
A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides
by: Biscoe, Mark R., et al.
Published: (2014) -
The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C–N Cross-Coupling
by: Liu, Richard Y, et al.
Published: (2021) -
Mild and General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts
by: Yang, Yang, et al.
Published: (2015)