Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects
Thesis: Ph. D. in Physical Chemistry, Massachusetts Institute of Technology, Department of Chemistry, 2015.
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| Format: | Thesis |
| Language: | eng |
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Massachusetts Institute of Technology
2015
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| Online Access: | http://hdl.handle.net/1721.1/98794 |
| _version_ | 1826193829586272256 |
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| author | Hontz, Eric Richard |
| author2 | Troy Van Voorhis. |
| author_facet | Troy Van Voorhis. Hontz, Eric Richard |
| author_sort | Hontz, Eric Richard |
| collection | MIT |
| description | Thesis: Ph. D. in Physical Chemistry, Massachusetts Institute of Technology, Department of Chemistry, 2015. |
| first_indexed | 2024-09-23T09:46:03Z |
| format | Thesis |
| id | mit-1721.1/98794 |
| institution | Massachusetts Institute of Technology |
| language | eng |
| last_indexed | 2024-09-23T09:46:03Z |
| publishDate | 2015 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/987942019-04-11T06:04:56Z Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects Electronic processes in OPVs : insights gained through modeling and MFEs Hontz, Eric Richard Troy Van Voorhis. Massachusetts Institute of Technology. Department of Chemistry. Massachusetts Institute of Technology. Department of Chemistry. Chemistry. Thesis: Ph. D. in Physical Chemistry, Massachusetts Institute of Technology, Department of Chemistry, 2015. Cataloged from PDF version of thesis. Includes bibliographical references (pages 185-232). Organic photovoltaics (OPVs) and organic light-emitting diodes (LEDs) are organic optoelectronics offering a number of unique benefits that may play an important role in the future of clean energy generation and efficient energy consumption. In this thesis, we explore key electronic processes in OPVs and OLEDs, with a major focus on quantum-mechanical kinetic modeling of magnetic field effects (MFEs) that probe underlying subprocesses. Certain organics are capable of dividing excited states in a process termed singlet fission, which can increase the maximum theoretical efficiency of an OPV by a factor of nearly 1/3. The MFEs on photocurrent measurements from our collaborators are combined with theoretical models to determine optimal device architectures for singlet fission OPVs, allowing us to exceed the conventional limit of one electron per photon. We also use MFEs to determine the spin of charge transfer states most efficient at generating photocurrent and demonstrate microscopic insight into the mechanism of their diffusion, offering new design principles for the engineering of donor-acceptor interfaces in OPVs. Thermally activated delayed fluorescence (TADF) is becoming an increasingly important OLED technology that extracts light from non-emissive triplet states via reverse intersystem crossing (RISC) to the bright singlet state. We use MFEs to prove a rather surprising finding that in TADF materials composed of donor-acceptor bends, the electron-hole distance fluctuates as a function of time, resulting in spontaneous cycling between states that are advantageous to fluorescence at one moment and then advantageous to RISC at another. Combined with additional topics in the fields of metal organic frameworks and reaction pathfinding methods, the work in this thesis provides insight into how to achieve optimal performance in OPV and OLED devices, which may serve an important role in the future of our energy landscape. by Eric Richard Hontz. Ph. D. in Physical Chemistry 2015-09-17T19:12:36Z 2015-09-17T19:12:36Z 2015 2015 Thesis http://hdl.handle.net/1721.1/98794 921143710 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 232 pages application/pdf Massachusetts Institute of Technology |
| spellingShingle | Chemistry. Hontz, Eric Richard Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects |
| title | Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects |
| title_full | Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects |
| title_fullStr | Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects |
| title_full_unstemmed | Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects |
| title_short | Electronic processes in organic optoelectronics : insights gained through modeling and magnetic field effects |
| title_sort | electronic processes in organic optoelectronics insights gained through modeling and magnetic field effects |
| topic | Chemistry. |
| url | http://hdl.handle.net/1721.1/98794 |
| work_keys_str_mv | AT hontzericrichard electronicprocessesinorganicoptoelectronicsinsightsgainedthroughmodelingandmagneticfieldeffects AT hontzericrichard electronicprocessesinopvsinsightsgainedthroughmodelingandmfes |