Solar-to-fuels conversion over In2O3/g-C3N4 hybrid photocatalysts

We have achieved in-situ growth of In2O3 nanocrystals onto the sheet-like g-C3N4 surface. The resulting In2O3-g-C3N4 hybrid structures exhibit considerable improvement on the photocatalytic activities for H2 generation and CO2 reduction. The enhanced activities are attributed to the interfacial tran...

Full description

Bibliographic Details
Main Authors: Liao, Yusen, Cao, Shao-Wen, Liu, Xin-Feng, Yuan, Yu-Peng, Zhang, Zhenyi, Fang, Jun, Loo, Say Chye Joachim, Sum, Tze Chien, Xue, Can
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/100079
http://hdl.handle.net/10220/17592
Description
Summary:We have achieved in-situ growth of In2O3 nanocrystals onto the sheet-like g-C3N4 surface. The resulting In2O3-g-C3N4 hybrid structures exhibit considerable improvement on the photocatalytic activities for H2 generation and CO2 reduction. The enhanced activities are attributed to the interfacial transfer of photogenerated electrons and holes between g-C3N4 and In2O3, leading to effective charge separation on both parts. Further studies by transient PL spectroscopy confirm that the In2O3-g-C3N4 heterojunctions remarkably promote the charge transfer efficiency, thereby increase the charge carrier lifetime for the photocatalytic reactions.