Non-aqueous energy storage devices using graphene nanosheets synthesized by green route

In this paper we report the use of triethylene glycol reduced graphene oxide (TRGO) as an electrode material for non-aqueous energy storage devices such as supercapacitors and Li-ion batteries. TRGO based non–aqueous symmetric supercapacitor is constructed and shown to deliver maximum energy and pow...

Full description

Bibliographic Details
Main Authors: Mhamane, Dattakumar, Suryawanshi, Anil, Banerjee, Abhik, Aravindan, Vanchiappan, Ogale, Satishchandra, Srinivasan, Madhavi
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/100325
http://hdl.handle.net/10220/10954
_version_ 1826129279229886464
author Mhamane, Dattakumar
Suryawanshi, Anil
Banerjee, Abhik
Aravindan, Vanchiappan
Ogale, Satishchandra
Srinivasan, Madhavi
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Mhamane, Dattakumar
Suryawanshi, Anil
Banerjee, Abhik
Aravindan, Vanchiappan
Ogale, Satishchandra
Srinivasan, Madhavi
author_sort Mhamane, Dattakumar
collection NTU
description In this paper we report the use of triethylene glycol reduced graphene oxide (TRGO) as an electrode material for non-aqueous energy storage devices such as supercapacitors and Li-ion batteries. TRGO based non–aqueous symmetric supercapacitor is constructed and shown to deliver maximum energy and power densities of 60.4 Wh kg–1 and 0.15 kW kg–1, respectively. More importantly, symmetric supercapacitor shows an extraordinary cycleability (5000 cycles) with over 80% of capacitance retention. In addition, Li-storage properties of TRGO are also evaluated in half-cell configuration (Li/TRGO) and shown to deliver a reversible capacity of ∼705 mAh g–1 with good cycleability at constant current density of 37 mA g–1. This result clearly suggests that green-synthesized graphene can be effectively used as a prospective electrode material for non-aqueous energy storage systems such as Li-ion batteries and supercapacitors.
first_indexed 2024-10-01T07:38:02Z
format Journal Article
id ntu-10356/100325
institution Nanyang Technological University
language English
last_indexed 2024-10-01T07:38:02Z
publishDate 2013
record_format dspace
spelling ntu-10356/1003252021-01-13T02:21:53Z Non-aqueous energy storage devices using graphene nanosheets synthesized by green route Mhamane, Dattakumar Suryawanshi, Anil Banerjee, Abhik Aravindan, Vanchiappan Ogale, Satishchandra Srinivasan, Madhavi School of Materials Science & Engineering Energy Research Institute @ NTU (ERI@N) In this paper we report the use of triethylene glycol reduced graphene oxide (TRGO) as an electrode material for non-aqueous energy storage devices such as supercapacitors and Li-ion batteries. TRGO based non–aqueous symmetric supercapacitor is constructed and shown to deliver maximum energy and power densities of 60.4 Wh kg–1 and 0.15 kW kg–1, respectively. More importantly, symmetric supercapacitor shows an extraordinary cycleability (5000 cycles) with over 80% of capacitance retention. In addition, Li-storage properties of TRGO are also evaluated in half-cell configuration (Li/TRGO) and shown to deliver a reversible capacity of ∼705 mAh g–1 with good cycleability at constant current density of 37 mA g–1. This result clearly suggests that green-synthesized graphene can be effectively used as a prospective electrode material for non-aqueous energy storage systems such as Li-ion batteries and supercapacitors. Published version 2013-07-05T01:29:40Z 2019-12-06T20:20:34Z 2013-07-05T01:29:40Z 2019-12-06T20:20:34Z 2013 2013 Journal Article Mhamane, D., Suryawanshi, A., Banerjee, A., Aravindan, V., Ogale, S., & Srinivasan, M. (2013). Non-aqueous energy storage devices using graphene nanosheets synthesized by green route. AIP Advances, 3(4). 2158-3226 https://hdl.handle.net/10356/100325 http://hdl.handle.net/10220/10954 10.1063/1.4802243 en AIP advances © 2013 The Authors. This paper was published in AIP Advances and is made available as an electronic reprint (preprint) with permission of The Authors. The paper can be found at the following official DOI: [http://dx.doi.org/10.1063/1.4802243]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law. application/pdf
spellingShingle Mhamane, Dattakumar
Suryawanshi, Anil
Banerjee, Abhik
Aravindan, Vanchiappan
Ogale, Satishchandra
Srinivasan, Madhavi
Non-aqueous energy storage devices using graphene nanosheets synthesized by green route
title Non-aqueous energy storage devices using graphene nanosheets synthesized by green route
title_full Non-aqueous energy storage devices using graphene nanosheets synthesized by green route
title_fullStr Non-aqueous energy storage devices using graphene nanosheets synthesized by green route
title_full_unstemmed Non-aqueous energy storage devices using graphene nanosheets synthesized by green route
title_short Non-aqueous energy storage devices using graphene nanosheets synthesized by green route
title_sort non aqueous energy storage devices using graphene nanosheets synthesized by green route
url https://hdl.handle.net/10356/100325
http://hdl.handle.net/10220/10954
work_keys_str_mv AT mhamanedattakumar nonaqueousenergystoragedevicesusinggraphenenanosheetssynthesizedbygreenroute
AT suryawanshianil nonaqueousenergystoragedevicesusinggraphenenanosheetssynthesizedbygreenroute
AT banerjeeabhik nonaqueousenergystoragedevicesusinggraphenenanosheetssynthesizedbygreenroute
AT aravindanvanchiappan nonaqueousenergystoragedevicesusinggraphenenanosheetssynthesizedbygreenroute
AT ogalesatishchandra nonaqueousenergystoragedevicesusinggraphenenanosheetssynthesizedbygreenroute
AT srinivasanmadhavi nonaqueousenergystoragedevicesusinggraphenenanosheetssynthesizedbygreenroute