Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/100998 http://hdl.handle.net/10220/13701 |
| _version_ | 1811694479480979456 |
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| author | Guo, Jia-Yi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Guo, Jia-Yi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai |
| author_sort | Guo, Jia-Yi |
| collection | NTU |
| description | The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯{C(O)N(Ar)}Sn+:] (3), and [(PPh2═NSiMe3)(PPh2═S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2–4 have been characterized by NMR spectroscopy and X-ray crystallography. |
| first_indexed | 2024-10-01T07:08:14Z |
| format | Journal Article |
| id | ntu-10356/100998 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:08:14Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/1009982020-03-07T12:34:52Z Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride Guo, Jia-Yi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai School of Physical and Mathematical Sciences The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯{C(O)N(Ar)}Sn+:] (3), and [(PPh2═NSiMe3)(PPh2═S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2–4 have been characterized by NMR spectroscopy and X-ray crystallography. 2013-09-25T08:05:49Z 2019-12-06T20:31:52Z 2013-09-25T08:05:49Z 2019-12-06T20:31:52Z 2012 2012 Journal Article Guo, J.-Y., Li, Y., Ganguly, R., & So, C.-K. (2012). Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide Complex toward Isocyanates and Rhodium(I) Chloride. Organometallics, 31(10), 3888–3893. https://hdl.handle.net/10356/100998 http://hdl.handle.net/10220/13701 10.1021/om300062n en Organometallics |
| spellingShingle | Guo, Jia-Yi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride |
| title | Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride |
| title_full | Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride |
| title_fullStr | Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride |
| title_full_unstemmed | Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride |
| title_short | Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride |
| title_sort | reactivity of a tin ii iminophosphinoyl thiophosphinoyl methanediide complex toward isocyanates and rhodium i chloride |
| url | https://hdl.handle.net/10356/100998 http://hdl.handle.net/10220/13701 |
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