Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts

Pt nanostructures are intensively studied for many environmental and energy applications. Their synthesis normally involves capping agents/organic species or the assistance of templates/substrates, making the preparation process complicated. Therefore, it is still challenging to obtain Pt nanostruct...

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Main Authors: Wu, Tian, Zhou, Hui Ming, Xia, Bao Yu, Xiao, Peng, Yan, Ya, Xie, Ming Shi, Wang, Xin
Other Authors: School of Chemical and Biomedical Engineering
Format: Journal Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/101268
http://hdl.handle.net/10220/19710
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author Wu, Tian
Zhou, Hui Ming
Xia, Bao Yu
Xiao, Peng
Yan, Ya
Xie, Ming Shi
Wang, Xin
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Wu, Tian
Zhou, Hui Ming
Xia, Bao Yu
Xiao, Peng
Yan, Ya
Xie, Ming Shi
Wang, Xin
author_sort Wu, Tian
collection NTU
description Pt nanostructures are intensively studied for many environmental and energy applications. Their synthesis normally involves capping agents/organic species or the assistance of templates/substrates, making the preparation process complicated. Therefore, it is still challenging to obtain Pt nanostructures with clean surface through a one-step surfactant-free method. We report herein the preparation of 3 D Pt nanodendrites with clean surface by a facile inorganic species assisted strategy. The possible specific adsorption of iron and nitrate ions would assist the growth of this 3 D Pt nanostructure. Thanks to its unique 3 D morphology composed of interconnected 1 D Pt nanorods/wires, the unsupported 3 D Pt nanodendrites exhibit higher stability and activity than commercial carbon black supported Pt nanoparticles and Pt black electrocatalysts for the oxygen reduction reaction and oxidation of small fuel molecules.
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spelling ntu-10356/1012682020-03-07T11:35:32Z Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts Wu, Tian Zhou, Hui Ming Xia, Bao Yu Xiao, Peng Yan, Ya Xie, Ming Shi Wang, Xin School of Chemical and Biomedical Engineering DRNTU::Engineering::Materials::Nanostructured materials Pt nanostructures are intensively studied for many environmental and energy applications. Their synthesis normally involves capping agents/organic species or the assistance of templates/substrates, making the preparation process complicated. Therefore, it is still challenging to obtain Pt nanostructures with clean surface through a one-step surfactant-free method. We report herein the preparation of 3 D Pt nanodendrites with clean surface by a facile inorganic species assisted strategy. The possible specific adsorption of iron and nitrate ions would assist the growth of this 3 D Pt nanostructure. Thanks to its unique 3 D morphology composed of interconnected 1 D Pt nanorods/wires, the unsupported 3 D Pt nanodendrites exhibit higher stability and activity than commercial carbon black supported Pt nanoparticles and Pt black electrocatalysts for the oxygen reduction reaction and oxidation of small fuel molecules. 2014-06-12T08:03:17Z 2019-12-06T20:35:50Z 2014-06-12T08:03:17Z 2019-12-06T20:35:50Z 2014 2014 Journal Article Wu, T., Zhou, H. M., Xia, B. Y., Xiao, P., Yan, Y., Xie, M. S., et al. (2014). Facile Synthesis of 3 D Platinum Dendrites with a Clean Surface as Highly Stable Electrocatalysts. ChemCatChem, 6(6), 1538-1542. 1867-3880 https://hdl.handle.net/10356/101268 http://hdl.handle.net/10220/19710 10.1002/cctc.201400058 en ChemCatChem © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
spellingShingle DRNTU::Engineering::Materials::Nanostructured materials
Wu, Tian
Zhou, Hui Ming
Xia, Bao Yu
Xiao, Peng
Yan, Ya
Xie, Ming Shi
Wang, Xin
Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts
title Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts
title_full Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts
title_fullStr Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts
title_full_unstemmed Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts
title_short Facile synthesis of 3 D platinum dendrites with a clean surface as highly stable electrocatalysts
title_sort facile synthesis of 3 d platinum dendrites with a clean surface as highly stable electrocatalysts
topic DRNTU::Engineering::Materials::Nanostructured materials
url https://hdl.handle.net/10356/101268
http://hdl.handle.net/10220/19710
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