Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
The reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computat...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/101625 http://hdl.handle.net/10220/18657 |
| _version_ | 1826126514580619264 |
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| author | Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee |
| author_sort | Kumaran, Elumalai |
| collection | NTU |
| description | The reaction of a terminal alkyne (RCCH) and 2-
aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2
afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C-
(CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution.
The reaction pathway has been examined through computational
studies. |
| first_indexed | 2024-10-01T06:53:54Z |
| format | Journal Article |
| id | ntu-10356/101625 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:53:54Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1016252023-02-28T19:42:20Z Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies. MOE (Min. of Education, S’pore) Accepted version 2014-01-21T08:19:58Z 2019-12-06T20:41:41Z 2014-01-21T08:19:58Z 2019-12-06T20:41:41Z 2013 2013 Journal Article Kumaran, E., How, K. T. S., Ganguly, R., Li, Y., & Leong, W. K. (2013). Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines. Organometallics, 32(15), 4149-4152. https://hdl.handle.net/10356/101625 http://hdl.handle.net/10220/18657 10.1021/om400326c en Organometallics © 2013 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om400326c]. 4p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines |
| title | Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines |
| title_full | Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines |
| title_fullStr | Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines |
| title_full_unstemmed | Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines |
| title_short | Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines |
| title_sort | synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2 aminopyridines |
| topic | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
| url | https://hdl.handle.net/10356/101625 http://hdl.handle.net/10220/18657 |
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