A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
Benzo[b]phosphole derivatives have attracted significant attention for their unique optoelectronic properties with potential for application in materials science. Herein we report a modular approach to a benzo[b]phosphole derivative based on a one-pot sequential coupling of an arylzinc reagent, an a...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
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| Online Access: | https://hdl.handle.net/10356/101670 http://hdl.handle.net/10220/19759 |
| _version_ | 1811688325751242752 |
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| author | Wu, Bin Santra, Mithun Yoshikai, Naohiko |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Wu, Bin Santra, Mithun Yoshikai, Naohiko |
| author_sort | Wu, Bin |
| collection | NTU |
| description | Benzo[b]phosphole derivatives have attracted significant attention for their unique optoelectronic properties with potential for application in materials science. Herein we report a modular approach to a benzo[b]phosphole derivative based on a one-pot sequential coupling of an arylzinc reagent, an alkyne, dichlorophenylphosphine (or phosphorus trichloride and a Grignard reagent), and an oxidant (for example H2O2, S, or Se). The approach allows for the construction of a library of previously inaccessible, structurally diverse benzo[b]phosphole derivatives with unprecedented ease. |
| first_indexed | 2024-10-01T05:30:25Z |
| format | Journal Article |
| id | ntu-10356/101670 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:30:25Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1016702020-03-07T12:34:53Z A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives Wu, Bin Santra, Mithun Yoshikai, Naohiko School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Benzo[b]phosphole derivatives have attracted significant attention for their unique optoelectronic properties with potential for application in materials science. Herein we report a modular approach to a benzo[b]phosphole derivative based on a one-pot sequential coupling of an arylzinc reagent, an alkyne, dichlorophenylphosphine (or phosphorus trichloride and a Grignard reagent), and an oxidant (for example H2O2, S, or Se). The approach allows for the construction of a library of previously inaccessible, structurally diverse benzo[b]phosphole derivatives with unprecedented ease. NRF (Natl Research Foundation, S’pore) 2014-06-13T06:32:44Z 2019-12-06T20:42:34Z 2014-06-13T06:32:44Z 2019-12-06T20:42:34Z 2014 2014 Journal Article Wu, B., Santra, M., & Yoshikai, N. (2014). A Highly Modular One-Pot Multicomponent Approach to Functionalized Benzo[ b ]phosphole Derivatives . Angewandte Chemie International Edition, 53(29), 7543-7546. 1433-7851 https://hdl.handle.net/10356/101670 http://hdl.handle.net/10220/19759 10.1002/anie.201404019 en Angewandte chemie international edition © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Science::Chemistry Wu, Bin Santra, Mithun Yoshikai, Naohiko A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives |
| title | A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives |
| title_full | A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives |
| title_fullStr | A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives |
| title_full_unstemmed | A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives |
| title_short | A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives |
| title_sort | highly modular one pot multicomponent approach to functionalized benzo b phosphole derivatives |
| topic | DRNTU::Science::Chemistry |
| url | https://hdl.handle.net/10356/101670 http://hdl.handle.net/10220/19759 |
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