Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline
Black wattle tannin (BWT), a typical natural plant polyphenol, was used as natural amphiphilic stabilizer to prepare BWT-stabilized Pd nanoparticles (BWT-Pd) catalyst. The as-prepared catalyst was found to be highly active in aqueous–organic biphasic hydrogenation of quinoline, which exhibited 100%...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/102284 http://hdl.handle.net/10220/16811 |
| _version_ | 1824454816463585280 |
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| author | Mao, Hui Ma, Jun Liao, Yang Zhao, Shilin Liao, Xuepin |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Mao, Hui Ma, Jun Liao, Yang Zhao, Shilin Liao, Xuepin |
| author_sort | Mao, Hui |
| collection | NTU |
| description | Black wattle tannin (BWT), a typical natural plant polyphenol, was used as natural amphiphilic stabilizer to prepare BWT-stabilized Pd nanoparticles (BWT-Pd) catalyst. The as-prepared catalyst was found to be highly active in aqueous–organic biphasic hydrogenation of quinoline, which exhibited 100% selectivity to 1,2,3,4-tetrahydroquinoline (py-THQ). Furthermore, the BWT-Pd catalyst can be reused 3 times without significant loss of catalytic activity, thus providing an effective and environmentally benign strategy for the production of py-THQ. |
| first_indexed | 2025-02-19T03:28:19Z |
| format | Journal Article |
| id | ntu-10356/102284 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T03:28:19Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/1022842020-06-01T10:26:47Z Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline Mao, Hui Ma, Jun Liao, Yang Zhao, Shilin Liao, Xuepin School of Materials Science & Engineering DRNTU::Engineering::Materials Black wattle tannin (BWT), a typical natural plant polyphenol, was used as natural amphiphilic stabilizer to prepare BWT-stabilized Pd nanoparticles (BWT-Pd) catalyst. The as-prepared catalyst was found to be highly active in aqueous–organic biphasic hydrogenation of quinoline, which exhibited 100% selectivity to 1,2,3,4-tetrahydroquinoline (py-THQ). Furthermore, the BWT-Pd catalyst can be reused 3 times without significant loss of catalytic activity, thus providing an effective and environmentally benign strategy for the production of py-THQ. 2013-10-24T07:54:24Z 2019-12-06T20:52:39Z 2013-10-24T07:54:24Z 2019-12-06T20:52:39Z 2013 2013 Journal Article Mao, H., Ma, J., Liao, Y., Zhao, S., & Liao, X. (2013). Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline. Catalysis science & technology, 3(6), 1612-1617. https://hdl.handle.net/10356/102284 http://hdl.handle.net/10220/16811 10.1039/c3cy00108c en Catalysis science & technology |
| spellingShingle | DRNTU::Engineering::Materials Mao, Hui Ma, Jun Liao, Yang Zhao, Shilin Liao, Xuepin Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline |
| title | Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline |
| title_full | Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline |
| title_fullStr | Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline |
| title_full_unstemmed | Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline |
| title_short | Using plant tannin as natural amphiphilic stabilizer to construct an aqueous–organic biphasic system for highly active and selective hydrogenation of quinoline |
| title_sort | using plant tannin as natural amphiphilic stabilizer to construct an aqueous organic biphasic system for highly active and selective hydrogenation of quinoline |
| topic | DRNTU::Engineering::Materials |
| url | https://hdl.handle.net/10356/102284 http://hdl.handle.net/10220/16811 |
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