Pillararene-based assemblies : design principle, preparation and applications
In this review, we highlight recent advancements on pillararene-based assemblies. The driving forces for the formation of the pillararene-based assemblies are discussed first. The host–guest interactions are deemed as not only general strategy for constructing assemblies but also essential component...
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
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| Online Access: | https://hdl.handle.net/10356/102580 http://hdl.handle.net/10220/19088 |
| _version_ | 1824456817323802624 |
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| author | Zhang, Huacheng Zhao, Yanli |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Zhang, Huacheng Zhao, Yanli |
| author_sort | Zhang, Huacheng |
| collection | NTU |
| description | In this review, we highlight recent advancements on pillararene-based assemblies. The driving forces for the formation of the pillararene-based assemblies are discussed first. The host–guest interactions are deemed as not only general strategy for constructing assemblies but also essential components for preventing the assemblies from the dissociation. Solvent effect is also important in the assembling process, since it could influence the host–guest interactions and provide solvophobic effect on pillararenes for the assembly. Then, several pillararene-based assembly architectures are introduced, including pillararene-based interlocked structures, such as (poly)pseudorotaxanes, (poly)rotaxanes, and daisy chains, classified by their topological structures and synthetic strategy. The morphologies of the supramolecular assemblies are divided into several types, for example, nanospheres, nanotubes and supramolecular polymers. Furthermore, the functions and potential applications are summarized accompanied with related assembly structures. The review not only provides fundamental findings, but also foresights future research directions in the research area of pillararene-based assemblies. |
| first_indexed | 2025-02-19T04:00:08Z |
| format | Journal Article |
| id | ntu-10356/102580 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T04:00:08Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1025802020-06-01T10:21:17Z Pillararene-based assemblies : design principle, preparation and applications Zhang, Huacheng Zhao, Yanli School of Materials Science & Engineering School of Physical and Mathematical Sciences DRNTU::Engineering::Materials In this review, we highlight recent advancements on pillararene-based assemblies. The driving forces for the formation of the pillararene-based assemblies are discussed first. The host–guest interactions are deemed as not only general strategy for constructing assemblies but also essential components for preventing the assemblies from the dissociation. Solvent effect is also important in the assembling process, since it could influence the host–guest interactions and provide solvophobic effect on pillararenes for the assembly. Then, several pillararene-based assembly architectures are introduced, including pillararene-based interlocked structures, such as (poly)pseudorotaxanes, (poly)rotaxanes, and daisy chains, classified by their topological structures and synthetic strategy. The morphologies of the supramolecular assemblies are divided into several types, for example, nanospheres, nanotubes and supramolecular polymers. Furthermore, the functions and potential applications are summarized accompanied with related assembly structures. The review not only provides fundamental findings, but also foresights future research directions in the research area of pillararene-based assemblies. 2014-04-03T06:48:50Z 2019-12-06T20:57:09Z 2014-04-03T06:48:50Z 2019-12-06T20:57:09Z 2013 2013 Journal Article Zhang, H., & Zhao, Y. (2013). Pillararene-based assemblies : design principle, preparation and applications. Chemistry - A European Journal, 19(50), 16862-16879. 0947-6539 https://hdl.handle.net/10356/102580 http://hdl.handle.net/10220/19088 10.1002/chem.201301635 en Chemistry - a European journal © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Engineering::Materials Zhang, Huacheng Zhao, Yanli Pillararene-based assemblies : design principle, preparation and applications |
| title | Pillararene-based assemblies : design principle, preparation and applications |
| title_full | Pillararene-based assemblies : design principle, preparation and applications |
| title_fullStr | Pillararene-based assemblies : design principle, preparation and applications |
| title_full_unstemmed | Pillararene-based assemblies : design principle, preparation and applications |
| title_short | Pillararene-based assemblies : design principle, preparation and applications |
| title_sort | pillararene based assemblies design principle preparation and applications |
| topic | DRNTU::Engineering::Materials |
| url | https://hdl.handle.net/10356/102580 http://hdl.handle.net/10220/19088 |
| work_keys_str_mv | AT zhanghuacheng pillararenebasedassembliesdesignprinciplepreparationandapplications AT zhaoyanli pillararenebasedassembliesdesignprinciplepreparationandapplications |