Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
| Main Authors: | , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/102607 http://hdl.handle.net/10220/19181 |
| _version_ | 1811677091992698880 |
|---|---|
| author | Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke |
| author_sort | Too, Pei Chui |
| collection | NTU |
| description | We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen. |
| first_indexed | 2024-10-01T02:31:52Z |
| format | Journal Article |
| id | ntu-10356/102607 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:31:52Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1026072023-02-28T19:23:07Z Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen. Published version 2014-04-09T05:19:27Z 2019-12-06T20:57:30Z 2014-04-09T05:19:27Z 2019-12-06T20:57:30Z 2013 2013 Journal Article Too, P. C., Tnay, Y. L., & Chiba, S. (2013). Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides. Beilstein Journal of Organic Chemistry, 9, 1217-1225. 1860-5397 https://hdl.handle.net/10356/102607 http://hdl.handle.net/10220/19181 10.3762/bjoc.9.138 23843917 en Beilstein journal of organic chemistry © 2013 Too et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry Too, Pei Chui Tnay, Ya Lin Chiba, Shunsuke Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides |
| title | Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides |
| title_full | Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides |
| title_fullStr | Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides |
| title_full_unstemmed | Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides |
| title_short | Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides |
| title_sort | copper catalyzed aerobic aliphatic c h oxygenation with hydroperoxides |
| topic | DRNTU::Science::Chemistry::Organic chemistry |
| url | https://hdl.handle.net/10356/102607 http://hdl.handle.net/10220/19181 |
| work_keys_str_mv | AT toopeichui coppercatalyzedaerobicaliphaticchoxygenationwithhydroperoxides AT tnayyalin coppercatalyzedaerobicaliphaticchoxygenationwithhydroperoxides AT chibashunsuke coppercatalyzedaerobicaliphaticchoxygenationwithhydroperoxides |