Using monovalent phosphorus compounds to form P-C bonds
User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl...
| Main Authors: | , |
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| Format: | Journal Article |
| Language: | English |
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2014
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| Online Access: | https://hdl.handle.net/10356/102735 http://hdl.handle.net/10220/19069 |
| _version_ | 1811691533694402560 |
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| author | Ng, Yong Xiang Mathey, Francois |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Ng, Yong Xiang Mathey, Francois |
| author_sort | Ng, Yong Xiang |
| collection | NTU |
| description | User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P[BOND]H bond that can be used for further transformations. |
| first_indexed | 2024-10-01T06:21:24Z |
| format | Journal Article |
| id | ntu-10356/102735 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:21:24Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1027352020-03-07T12:34:54Z Using monovalent phosphorus compounds to form P-C bonds Ng, Yong Xiang Mathey, Francois School of Physical and Mathematical Sciences DRNTU::Science::Physics User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P[BOND]H bond that can be used for further transformations. 2014-04-01T08:18:37Z 2019-12-06T20:59:42Z 2014-04-01T08:18:37Z 2019-12-06T20:59:42Z 2013 2013 Journal Article Ng, Y. X., & Mathey, F. (2013). Using Monovalent Phosphorus Compounds to Form P-C Bonds. Angewandte Chemie International Edition, 52(52), 14140-14142. 1433-7851 https://hdl.handle.net/10356/102735 http://hdl.handle.net/10220/19069 10.1002/anie.201306643 en Angewandte chemie international edition © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Science::Physics Ng, Yong Xiang Mathey, Francois Using monovalent phosphorus compounds to form P-C bonds |
| title | Using monovalent phosphorus compounds to form P-C bonds |
| title_full | Using monovalent phosphorus compounds to form P-C bonds |
| title_fullStr | Using monovalent phosphorus compounds to form P-C bonds |
| title_full_unstemmed | Using monovalent phosphorus compounds to form P-C bonds |
| title_short | Using monovalent phosphorus compounds to form P-C bonds |
| title_sort | using monovalent phosphorus compounds to form p c bonds |
| topic | DRNTU::Science::Physics |
| url | https://hdl.handle.net/10356/102735 http://hdl.handle.net/10220/19069 |
| work_keys_str_mv | AT ngyongxiang usingmonovalentphosphoruscompoundstoformpcbonds AT matheyfrancois usingmonovalentphosphoruscompoundstoformpcbonds |